Synthesis of 1,1-organodiboronates via Rh(I)CI-catalyzed sequential regioselective hydroboration of 1-alkynes

Kohei Endo; Munenao Hirokami; Takanori Shibata

doi:10.1055/s-0028-1088131

Synthesis of 1,1-organodiboronates via Rh(I)CI-catalyzed sequential regioselective hydroboration of 1-alkynes

Kohei Endo^*, Munenao Hirokami, Takanori Shibata

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

74 Citations (Scopus)

Abstract

A Rh(I)Cl-DPPB-complex-catalyzed sequential hydroboration of aryl alkynes and aliphatic alkynes was achieved. The reaction proceeded with almost perfect regioselectivity to afford 1,1-organodiboronate compounds in moderate to good yield.

Original language	English
Pages (from-to)	1331-1335
Number of pages	5
Journal	Synlett
Issue number	8
DOIs	https://doi.org/10.1055/s-0028-1088131
Publication status	Published - 2009 May

Keywords

Alkynes
Hydroborations
Regioselectivity
Rhodium

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-0028-1088131

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title = "Synthesis of 1,1-organodiboronates via Rh(I)CI-catalyzed sequential regioselective hydroboration of 1-alkynes",

abstract = "A Rh(I)Cl-DPPB-complex-catalyzed sequential hydroboration of aryl alkynes and aliphatic alkynes was achieved. The reaction proceeded with almost perfect regioselectivity to afford 1,1-organodiboronate compounds in moderate to good yield.",

keywords = "Alkynes, Hydroborations, Regioselectivity, Rhodium",

author = "Kohei Endo and Munenao Hirokami and Takanori Shibata",

year = "2009",

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doi = "10.1055/s-0028-1088131",

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AU - Endo, Kohei

AU - Hirokami, Munenao

AU - Shibata, Takanori

PY - 2009/5

Y1 - 2009/5

N2 - A Rh(I)Cl-DPPB-complex-catalyzed sequential hydroboration of aryl alkynes and aliphatic alkynes was achieved. The reaction proceeded with almost perfect regioselectivity to afford 1,1-organodiboronate compounds in moderate to good yield.

AB - A Rh(I)Cl-DPPB-complex-catalyzed sequential hydroboration of aryl alkynes and aliphatic alkynes was achieved. The reaction proceeded with almost perfect regioselectivity to afford 1,1-organodiboronate compounds in moderate to good yield.

KW - Alkynes

KW - Hydroborations

KW - Regioselectivity

KW - Rhodium

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U2 - 10.1055/s-0028-1088131

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Synthesis of 1,1-organodiboronates via Rh(I)CI-catalyzed sequential regioselective hydroboration of 1-alkynes

Abstract

Keywords

ASJC Scopus subject areas

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