TY - JOUR
T1 - SYNTHESIS OF ALKYL METHACRYLATE COPOLYMERS BY ANIONIC POLYMERIZATION.
AU - Allen, R. D.
AU - Smith, S. D.
AU - Long, Timothy Edward
AU - McGrath, J. E.
PY - 1985/4/1
Y1 - 1985/4/1
N2 - By taking advantage of a novel purification route to anionic polymerization grade alkyl methacrylate monomers, clean block copolymers have been synthesized in high yields with very low compositional heterogeneity and narrow polydispersities. Both hydrocarbon-methacrylate and all-acrylic block copolymers have been synthesized. The study of the solid state properties of these glass-glass block systems indicate that the amount of phase mixing may be controlled by varying the block molecular weight and differential solubility of the constituent blocks.
AB - By taking advantage of a novel purification route to anionic polymerization grade alkyl methacrylate monomers, clean block copolymers have been synthesized in high yields with very low compositional heterogeneity and narrow polydispersities. Both hydrocarbon-methacrylate and all-acrylic block copolymers have been synthesized. The study of the solid state properties of these glass-glass block systems indicate that the amount of phase mixing may be controlled by varying the block molecular weight and differential solubility of the constituent blocks.
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M3 - Conference article
AN - SCOPUS:0022048802
SN - 0032-3934
VL - 26
SP - 247
EP - 248
JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
IS - 1
ER -