TY - JOUR
T1 - Synthesis of poly(2,5-dimethylphenylene sulfide) through oxidative polymerization of sulfur chloride with p-xylene
AU - Miyatake, Kenji
AU - Jikei, Mitsutoshi
AU - Katoh, Junya
AU - Yamamoto, Kimihisa
AU - Nishide, Hiroyuki
AU - Tsuchida, Eishun
PY - 1994/4
Y1 - 1994/4
N2 - Poly(2,5-dimethylphenylene sulfide) was prepared by oxidative polymerization of sulfur chloride with p-xylene using 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) as an oxidizing agent. The reaction proceeded efficiently under atmospheric pressure and at room temperature. The polymer formed had a high melting temperature and linear structure which was confirmed by spectroscopies. The effects of reaction time, solvent, temperature and oxidizing agent on polymerization are also discussed.
AB - Poly(2,5-dimethylphenylene sulfide) was prepared by oxidative polymerization of sulfur chloride with p-xylene using 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) as an oxidizing agent. The reaction proceeded efficiently under atmospheric pressure and at room temperature. The polymer formed had a high melting temperature and linear structure which was confirmed by spectroscopies. The effects of reaction time, solvent, temperature and oxidizing agent on polymerization are also discussed.
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U2 - 10.1002/pat.1994.220050402
DO - 10.1002/pat.1994.220050402
M3 - Article
AN - SCOPUS:0028413443
SN - 1042-7147
VL - 5
SP - 216
EP - 220
JO - Polymers for Advanced Technologies
JF - Polymers for Advanced Technologies
IS - 4
ER -