Synthesis of poly(oxoammonium salt)s and their electrical properties in the organic thin film device

Takeo Suga; Shunya Takeuchi; Takanori Ozaki; Miki Sakata; Kenichi Oyaizu; Hiroyuki Nishide

doi:10.1246/cl.2009.1160

Synthesis of poly(oxoammonium salt)s and their electrical properties in the organic thin film device

Takeo Suga, Shunya Takeuchi, Takanori Ozaki, Miki Sakata, Kenichi Oyaizu, Hiroyuki Nishide^*

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

Two redox-active poly(oxoammonium salt)s were synthesized via chemical oxidation of a TEMPO-substituted polymer, or conventional radical polymerization of the oxoammonium monomer, respectively. The diode-structured thin film device composed of poly(oxoammonium salt) with radical cone, of 643% exhibited a resistive switching behavior (ON-OFF ratio >10³), in contrast to the radical-free poly(oxoammonium salt), which revealed that the coexistence of radical/oxoammonium salts contributed to a significant change in I-V characteristics.

Original language	English
Pages (from-to)	1160-1161
Number of pages	2
Journal	Chemistry Letters
Volume	38
Issue number	12
DOIs	https://doi.org/10.1246/cl.2009.1160
Publication status	Published - 2009

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1246/cl.2009.1160

Cite this

@article{5fdeac3d890644269d4918c39258c242,

title = "Synthesis of poly(oxoammonium salt)s and their electrical properties in the organic thin film device",

abstract = "Two redox-active poly(oxoammonium salt)s were synthesized via chemical oxidation of a TEMPO-substituted polymer, or conventional radical polymerization of the oxoammonium monomer, respectively. The diode-structured thin film device composed of poly(oxoammonium salt) with radical cone, of 643% exhibited a resistive switching behavior (ON-OFF ratio >103), in contrast to the radical-free poly(oxoammonium salt), which revealed that the coexistence of radical/oxoammonium salts contributed to a significant change in I-V characteristics.",

author = "Takeo Suga and Shunya Takeuchi and Takanori Ozaki and Miki Sakata and Kenichi Oyaizu and Hiroyuki Nishide",

year = "2009",

doi = "10.1246/cl.2009.1160",

language = "English",

volume = "38",

pages = "1160--1161",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

number = "12",

}

TY - JOUR

T1 - Synthesis of poly(oxoammonium salt)s and their electrical properties in the organic thin film device

AU - Suga, Takeo

AU - Takeuchi, Shunya

AU - Ozaki, Takanori

AU - Sakata, Miki

AU - Oyaizu, Kenichi

AU - Nishide, Hiroyuki

PY - 2009

Y1 - 2009

N2 - Two redox-active poly(oxoammonium salt)s were synthesized via chemical oxidation of a TEMPO-substituted polymer, or conventional radical polymerization of the oxoammonium monomer, respectively. The diode-structured thin film device composed of poly(oxoammonium salt) with radical cone, of 643% exhibited a resistive switching behavior (ON-OFF ratio >103), in contrast to the radical-free poly(oxoammonium salt), which revealed that the coexistence of radical/oxoammonium salts contributed to a significant change in I-V characteristics.

AB - Two redox-active poly(oxoammonium salt)s were synthesized via chemical oxidation of a TEMPO-substituted polymer, or conventional radical polymerization of the oxoammonium monomer, respectively. The diode-structured thin film device composed of poly(oxoammonium salt) with radical cone, of 643% exhibited a resistive switching behavior (ON-OFF ratio >103), in contrast to the radical-free poly(oxoammonium salt), which revealed that the coexistence of radical/oxoammonium salts contributed to a significant change in I-V characteristics.

UR - http://www.scopus.com/inward/record.url?scp=72449141011&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=72449141011&partnerID=8YFLogxK

U2 - 10.1246/cl.2009.1160

DO - 10.1246/cl.2009.1160

M3 - Article

AN - SCOPUS:72449141011

SN - 0366-7022

VL - 38

SP - 1160

EP - 1161

JO - Chemistry Letters

JF - Chemistry Letters

IS - 12

ER -

Synthesis of poly(oxoammonium salt)s and their electrical properties in the organic thin film device

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this