Synthesis of star-like BiVO4 photocatalysts by organic-aqueous hetero-phase reaction: Interaction between bismuth and amino group of oleylamine

Taisei Hangai; Namiki Uchiyama; Takuya Hasegawa; Yusuke Asakura; Shu Yin

doi:10.1142/S1793604722500205

Synthesis of star-like BiVO₄ photocatalysts by organic-aqueous hetero-phase reaction: Interaction between bismuth and amino group of oleylamine

Taisei Hangai, Namiki Uchiyama, Takuya Hasegawa, Yusuke Asakura, Shu Yin^*

^*Corresponding author for this work

Kagami Memorial Research Institute for Materials Science and Technology

Research output: Contribution to journal › Article › peer-review

Abstract

The bismuth vanadate (BiVO4) photocatalyst was successfully synthesized by an organic-aqueous hetero-phase reaction method using organic additives (oleic acid, oleyl alcohol, and oleylamine) to investigate the reaction mechanism. The BiVO4 with a star-like morphology could be synthesized with oleylamine. Bismuth precursors formed by the interaction between bismuth and the amino group of oleylamine were nano-sized complex particles with amorphous phase, finally resulted in the formation of star-like morphology. Moreover, BiVO4 synthesized with oleylamine showed excellent photocatalytic activity on degradation of rhodamine B.

Original language	English
Article number	2250020
Journal	Functional Materials Letters
Volume	15
Issue number	4
DOIs	https://doi.org/10.1142/S1793604722500205
Publication status	Published - 2022 May 1

Keywords

BiVO
Organic-aqueous hetero-phase reaction
Photocatalysts

ASJC Scopus subject areas

Materials Science(all)

Access to Document

10.1142/S1793604722500205

Cite this

@article{bb8eba6c5b8c4e99a34141204ab3cf88,

title = "Synthesis of star-like BiVO4 photocatalysts by organic-aqueous hetero-phase reaction: Interaction between bismuth and amino group of oleylamine",

abstract = "The bismuth vanadate (BiVO4) photocatalyst was successfully synthesized by an organic-aqueous hetero-phase reaction method using organic additives (oleic acid, oleyl alcohol, and oleylamine) to investigate the reaction mechanism. The BiVO4 with a star-like morphology could be synthesized with oleylamine. Bismuth precursors formed by the interaction between bismuth and the amino group of oleylamine were nano-sized complex particles with amorphous phase, finally resulted in the formation of star-like morphology. Moreover, BiVO4 synthesized with oleylamine showed excellent photocatalytic activity on degradation of rhodamine B.",

keywords = "BiVO, Organic-aqueous hetero-phase reaction, Photocatalysts",

author = "Taisei Hangai and Namiki Uchiyama and Takuya Hasegawa and Yusuke Asakura and Shu Yin",

note = "Funding Information: This work was supported by the Japan Society funded the present work for the Promotion of Science (JSPS) Grant-inAid for the Scientifc Research (KAKENHI, Nos. 16H06439; 20H00297), and by The Dynamic Alliance for Open Innovations Bridging Human, Environment and Materials, and the Cooperative Research Program of {"}Network Joint Research Center for Materials and Devices{"}. Publisher Copyright: {\textcopyright} 2022 World Scientific Publishing Company.",

year = "2022",

month = may,

day = "1",

doi = "10.1142/S1793604722500205",

language = "English",

volume = "15",

journal = "Functional Materials Letters",

issn = "1793-6047",

publisher = "World Scientific Publishing Co. Pte Ltd",

number = "4",

}

TY - JOUR

T1 - Synthesis of star-like BiVO4 photocatalysts by organic-aqueous hetero-phase reaction

T2 - Interaction between bismuth and amino group of oleylamine

AU - Hangai, Taisei

AU - Uchiyama, Namiki

AU - Hasegawa, Takuya

AU - Asakura, Yusuke

AU - Yin, Shu

N1 - Funding Information: This work was supported by the Japan Society funded the present work for the Promotion of Science (JSPS) Grant-inAid for the Scientifc Research (KAKENHI, Nos. 16H06439; 20H00297), and by The Dynamic Alliance for Open Innovations Bridging Human, Environment and Materials, and the Cooperative Research Program of "Network Joint Research Center for Materials and Devices". Publisher Copyright: © 2022 World Scientific Publishing Company.

PY - 2022/5/1

Y1 - 2022/5/1

N2 - The bismuth vanadate (BiVO4) photocatalyst was successfully synthesized by an organic-aqueous hetero-phase reaction method using organic additives (oleic acid, oleyl alcohol, and oleylamine) to investigate the reaction mechanism. The BiVO4 with a star-like morphology could be synthesized with oleylamine. Bismuth precursors formed by the interaction between bismuth and the amino group of oleylamine were nano-sized complex particles with amorphous phase, finally resulted in the formation of star-like morphology. Moreover, BiVO4 synthesized with oleylamine showed excellent photocatalytic activity on degradation of rhodamine B.

AB - The bismuth vanadate (BiVO4) photocatalyst was successfully synthesized by an organic-aqueous hetero-phase reaction method using organic additives (oleic acid, oleyl alcohol, and oleylamine) to investigate the reaction mechanism. The BiVO4 with a star-like morphology could be synthesized with oleylamine. Bismuth precursors formed by the interaction between bismuth and the amino group of oleylamine were nano-sized complex particles with amorphous phase, finally resulted in the formation of star-like morphology. Moreover, BiVO4 synthesized with oleylamine showed excellent photocatalytic activity on degradation of rhodamine B.

KW - BiVO

KW - Organic-aqueous hetero-phase reaction

KW - Photocatalysts

UR - http://www.scopus.com/inward/record.url?scp=85132517370&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85132517370&partnerID=8YFLogxK

U2 - 10.1142/S1793604722500205

DO - 10.1142/S1793604722500205

M3 - Article

AN - SCOPUS:85132517370

SN - 1793-6047

VL - 15

JO - Functional Materials Letters

JF - Functional Materials Letters

IS - 4

M1 - 2250020

ER -