Synthesis of two Diastereoisomers of A/B Fragment of Ciguatoxin

Seijiro Hosokawa; Minoru Isobe

doi:10.1055/s-1995-5225

Synthesis of two Diastereoisomers of A/B Fragment of Ciguatoxin

Seijiro Hosokawa, Minoru Isobe^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

69 Citations (Scopus)

Abstract

Synthesis of 2 diastereoisomers of A/B fragments of ciguatoxin was achieved by connecting a hexose and 2 pentose derivatives with silylacetylene. The key steps are the cationic cyclization and reductive decomplexation of the acetylene biscobalthexacarbonyl complex.

Original language	English
Pages (from-to)	1179-1180
Number of pages	2
Journal	Synlett
Volume	1995
Issue number	11
DOIs	https://doi.org/10.1055/s-1995-5225
Publication status	Published - 1995 Nov 1
Externally published	Yes

Keywords

Two diastereoisomers were synthesized from D-glucose and D-arabinose or L-xylose derivatives as partial model compounds for the A/B ring of ciguatoxin.

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-1995-5225

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abstract = "Synthesis of 2 diastereoisomers of A/B fragments of ciguatoxin was achieved by connecting a hexose and 2 pentose derivatives with silylacetylene. The key steps are the cationic cyclization and reductive decomplexation of the acetylene biscobalthexacarbonyl complex.",

keywords = "Two diastereoisomers were synthesized from D-glucose and D-arabinose or L-xylose derivatives as partial model compounds for the A/B ring of ciguatoxin.",

author = "Seijiro Hosokawa and Minoru Isobe",

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AU - Isobe, Minoru

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AB - Synthesis of 2 diastereoisomers of A/B fragments of ciguatoxin was achieved by connecting a hexose and 2 pentose derivatives with silylacetylene. The key steps are the cationic cyclization and reductive decomplexation of the acetylene biscobalthexacarbonyl complex.

KW - Two diastereoisomers were synthesized from D-glucose and D-arabinose or L-xylose derivatives as partial model compounds for the A/B ring of ciguatoxin.

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Synthesis of two Diastereoisomers of A/B Fragment of Ciguatoxin

Abstract

Keywords

ASJC Scopus subject areas

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