@article{2d0e43e4f72c4f3e9d3e02262b36e738,
title = "The first total synthesis and structural determination of TMC-264",
abstract = "The first total synthesis and structural determination of TMC-264 has been accomplished. Regioselective bromination, regioselective methoxymethylation, and nickel(0)-Lewis acid-mediated cyclization afforded multi-functionalized 1-methyl-dibenzo[b,d]-pyran skeleton.",
keywords = "Absolute configuration, Antiallergic agent, Biaryl coupling, Regioselective methoxymethylation, TMC-264, Total synthesis",
author = "Kuniaki Tatsuta and Akiho Furuyama and Tomoe Yano and Yasuaki Suzuki and Takashi Ogura and Seijiro Hosokawa",
note = "Funding Information: This work was financially supported by the Consolidated Research Institute for Advanced Science and Medical Care, the Global COE program {\textquoteleft}Center for Practical Chemical Wisdom{\textquoteright}, and Scientific Research on Priority Area {\textquoteleft}Creation of Biologically Functional Molecules{\textquoteright} from the Ministry of Education, Culture, Sports, Science and Technology. ",
year = "2008",
month = jun,
day = "16",
doi = "10.1016/j.tetlet.2008.04.074",
language = "English",
volume = "49",
pages = "4036--4039",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Ltd",
number = "25",
}