The moment of initial crystallization captured on functionalized nanoparticles

Hironobu Machida*, Takeshi Sugahara, Izumi Hirasawa

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)


Even if a liquid is cooled below its melting point, the liquid state can be maintained under certain conditions. This state is called supercooling. Spraying fine particles of dry ice or silver iodide induces a phase change from supercooled droplets to ice grains. However, the mechanism by which crystallization seeds diminish supercooling is not well understood. Here, we captured the moment when a cluster, which is the smallest structural unit of a crystal, envelops a silver nanoparticle. As a result of observing the structure of a supercooled aqueous solution of a clathrate hydrate, we found that silver nanoparticles accelerate the formation of clusters, whereas the noble metals palladium, gold and iridium likewise form nanoparticles but do not promote crystallization. Our discoveries elucidate the mechanism of heterogeneous nucleation during a phase change in clathrate hydrates. We anticipate our discovery to be the starting point for the control of supercooling, a technique that can be applied to enhance the production efficiency and quality of manufactured products.

Original languageEnglish
Article number66
JournalCommunications Materials
Issue number1
Publication statusPublished - 2021 Dec

ASJC Scopus subject areas

  • General Materials Science
  • Mechanics of Materials


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