TY - JOUR
T1 - The Oxidative Polymerization of 2, 6-Dimethylphenol with a Copper-Pyridine Complex in the Presence of 2, 2-Bis(4-hydroxy-3, 5-dimethylphenyl)propane
AU - Hyun, Sang Heon
AU - Maekawa, Toshihiko
AU - Nishide, Hiroyuki
AU - Tsuchida, Eishun
PY - 1985
Y1 - 1985
N2 - 2, 6-Dimethylphenol (DMP) was oxidatively polymerized with a copper-pyridine complex in the presence of 2,2-bis(4-hydroxy-3,5-dimethylphenyl)propane (BP). The polymerization gave the poly(2, 6-dimethyl-l, 4-phenylene oxide) having phenolic hydroxyl groups on both the chain ends. From kinetics and spectroscopic analyses of the polymerization, the polymerization mechanism has been disclosed as follows: BP preferentially coordinated to the copper catalyst is activated first, and then reacts with the subsequently activated DMP to give the polymer.
AB - 2, 6-Dimethylphenol (DMP) was oxidatively polymerized with a copper-pyridine complex in the presence of 2,2-bis(4-hydroxy-3,5-dimethylphenyl)propane (BP). The polymerization gave the poly(2, 6-dimethyl-l, 4-phenylene oxide) having phenolic hydroxyl groups on both the chain ends. From kinetics and spectroscopic analyses of the polymerization, the polymerization mechanism has been disclosed as follows: BP preferentially coordinated to the copper catalyst is activated first, and then reacts with the subsequently activated DMP to give the polymer.
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U2 - 10.1246/nikkashi.1985.238
DO - 10.1246/nikkashi.1985.238
M3 - Article
AN - SCOPUS:85008560172
SN - 0369-4577
VL - 1985
SP - 238
EP - 241
JO - Nippon Kagaku Kaishi / Chemical Society of Japan - Chemistry and Industrial Chemistry Journal
JF - Nippon Kagaku Kaishi / Chemical Society of Japan - Chemistry and Industrial Chemistry Journal
IS - 2
ER -