The single crystal metal-non-aqueous solvent interface. Underpotential deposition of Cd on Ag (111) in propylene carbonate

Xing Xue-Kun; P. Abel; R. McIntyre; Daniel Alberto Scherson

doi:10.1016/0022-0728(87)80212-7

The single crystal metal-non-aqueous solvent interface. Underpotential deposition of Cd on Ag (111) in propylene carbonate

Xing Xue-Kun^*, P. Abel, R. McIntyre, Daniel Alberto Scherson

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

The underpotential deposition of cadmium on Ag (111) in propylene carbonate using either lithium perchlorate or tetra-n-butylammonium perchlorate as supporting electrolytes has been found to yield sharp and well defined voltammetric peaks. The results obtained in aqueous LiClO₄ and tetraethylammonium perchlorate solutions for the same UPD-host metal system were, however, found to be different from those in propylene carbonate, particularly in the case of LiClO₄ for which the voltammetry was characterized by broad and ill-defined features. This novel solvent-induced effect has been attributed to differences in the extent of specific adsorption of the perchlorate anion in water and PC and/or to solvent-metal substrate interactions.

Original language	English
Pages (from-to)	261-271
Number of pages	11
Journal	Journal of Electroanalytical Chemistry
Volume	216
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-0728(87)80212-7
Publication status	Published - 1987 Sept 1
Externally published	Yes

ASJC Scopus subject areas

Analytical Chemistry
Chemical Engineering(all)
Electrochemistry

Access to Document

10.1016/0022-0728(87)80212-7

Cite this

@article{d3a30a77b7ff44849e793c74f2cb941c,

title = "The single crystal metal-non-aqueous solvent interface. Underpotential deposition of Cd on Ag (111) in propylene carbonate",

abstract = "The underpotential deposition of cadmium on Ag (111) in propylene carbonate using either lithium perchlorate or tetra-n-butylammonium perchlorate as supporting electrolytes has been found to yield sharp and well defined voltammetric peaks. The results obtained in aqueous LiClO4 and tetraethylammonium perchlorate solutions for the same UPD-host metal system were, however, found to be different from those in propylene carbonate, particularly in the case of LiClO4 for which the voltammetry was characterized by broad and ill-defined features. This novel solvent-induced effect has been attributed to differences in the extent of specific adsorption of the perchlorate anion in water and PC and/or to solvent-metal substrate interactions.",

author = "Xing Xue-Kun and P. Abel and R. McIntyre and Scherson, {Daniel Alberto}",

year = "1987",

month = sep,

day = "1",

doi = "10.1016/0022-0728(87)80212-7",

language = "English",

volume = "216",

pages = "261--271",

journal = "Journal of Electroanalytical Chemistry",

issn = "0022-0728",

publisher = "Elsevier Sequoia",

number = "1-2",

}

TY - JOUR

T1 - The single crystal metal-non-aqueous solvent interface. Underpotential deposition of Cd on Ag (111) in propylene carbonate

AU - Xue-Kun, Xing

AU - Abel, P.

AU - McIntyre, R.

AU - Scherson, Daniel Alberto

PY - 1987/9/1

Y1 - 1987/9/1

N2 - The underpotential deposition of cadmium on Ag (111) in propylene carbonate using either lithium perchlorate or tetra-n-butylammonium perchlorate as supporting electrolytes has been found to yield sharp and well defined voltammetric peaks. The results obtained in aqueous LiClO4 and tetraethylammonium perchlorate solutions for the same UPD-host metal system were, however, found to be different from those in propylene carbonate, particularly in the case of LiClO4 for which the voltammetry was characterized by broad and ill-defined features. This novel solvent-induced effect has been attributed to differences in the extent of specific adsorption of the perchlorate anion in water and PC and/or to solvent-metal substrate interactions.

AB - The underpotential deposition of cadmium on Ag (111) in propylene carbonate using either lithium perchlorate or tetra-n-butylammonium perchlorate as supporting electrolytes has been found to yield sharp and well defined voltammetric peaks. The results obtained in aqueous LiClO4 and tetraethylammonium perchlorate solutions for the same UPD-host metal system were, however, found to be different from those in propylene carbonate, particularly in the case of LiClO4 for which the voltammetry was characterized by broad and ill-defined features. This novel solvent-induced effect has been attributed to differences in the extent of specific adsorption of the perchlorate anion in water and PC and/or to solvent-metal substrate interactions.

UR - http://www.scopus.com/inward/record.url?scp=0347548498&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0347548498&partnerID=8YFLogxK

U2 - 10.1016/0022-0728(87)80212-7

DO - 10.1016/0022-0728(87)80212-7

M3 - Article

AN - SCOPUS:0347548498

SN - 0022-0728

VL - 216

SP - 261

EP - 271

JO - Journal of Electroanalytical Chemistry

JF - Journal of Electroanalytical Chemistry

IS - 1-2

ER -

The single crystal metal-non-aqueous solvent interface. Underpotential deposition of Cd on Ag (111) in propylene carbonate

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this