TY - JOUR
T1 - Total synthesis of (+)-epoxyquinols A and B
AU - Shoji, Mitsuru
AU - Yamaguchi, Junichiro
AU - Kakeya, Hideaki
AU - Osada, Hiroyuki
AU - Hayashi, Yujiro
PY - 2002/9/2
Y1 - 2002/9/2
N2 - A highly stereoselective HfCl4-mediated Diels-Alder reaction of furan and the chiral acrylate ester of Corey's auxiliary to subsequently give 1, and the realization of the postulated biosynthetic pathway for the construction of epoxyquinols A and B, namely, oxidative 6π electrocyclization, followed by Diels-Alder reaction of the unprotected monomer are the key steps in the asymmetric total synthesis of (+)-epoxyquinols A and B.
AB - A highly stereoselective HfCl4-mediated Diels-Alder reaction of furan and the chiral acrylate ester of Corey's auxiliary to subsequently give 1, and the realization of the postulated biosynthetic pathway for the construction of epoxyquinols A and B, namely, oxidative 6π electrocyclization, followed by Diels-Alder reaction of the unprotected monomer are the key steps in the asymmetric total synthesis of (+)-epoxyquinols A and B.
KW - Asymmetric synthesis
KW - Diels-Alder reaction
KW - Dimerization
KW - Epoxyquinol
KW - Total synthesis
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U2 - 10.1002/1521-3773(20020902)41:17<3192::AID-ANIE3192>3.0.CO;2-E
DO - 10.1002/1521-3773(20020902)41:17<3192::AID-ANIE3192>3.0.CO;2-E
M3 - Article
C2 - 12207386
AN - SCOPUS:0037008978
SN - 1433-7851
VL - 41
SP - 3192
EP - 3194
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 17
ER -