Total Synthesis of (‒)-Grayanotoxin III

Toshiyuki Kan; Seijiro Hosokawa; Shinji Nara; Masato Oikawa; Shinya Ito; Fuyuhiko Matsuda; Haruhisa Shirahama

doi:10.1021/jo00098a009

Total Synthesis of (‒)-Grayanotoxin III

Toshiyuki Kan, Seijiro Hosokawa, Shinji Nara, Masato Oikawa, Shinya Ito, Fuyuhiko Matsuda^*, Haruhisa Shirahama

^*Corresponding author for this work

Research output: Contribution to journal › Letter › peer-review

118 Citations (Scopus)

Abstract

Total synthesis of (‒)-grayanotoxin III (3), a unique tetracyclic diterpene isolated from the leaves of various plants of the family Ericaceae, has been successfully accomplished featuring the highly stereoselective cyclization reactions induced by SmI₂.

Original language	English
Pages (from-to)	5532-5534
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	59
Issue number	19
DOIs	https://doi.org/10.1021/jo00098a009
Publication status	Published - 1994 Sept 1
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.1021/jo00098a009

Cite this

@article{8366c431f6b446a2b5f8a0694c64d364,

title = "Total Synthesis of (‒)-Grayanotoxin III",

abstract = "Total synthesis of (‒)-grayanotoxin III (3), a unique tetracyclic diterpene isolated from the leaves of various plants of the family Ericaceae, has been successfully accomplished featuring the highly stereoselective cyclization reactions induced by SmI2.",

author = "Toshiyuki Kan and Seijiro Hosokawa and Shinji Nara and Masato Oikawa and Shinya Ito and Fuyuhiko Matsuda and Haruhisa Shirahama",

year = "1994",

month = sep,

day = "1",

doi = "10.1021/jo00098a009",

language = "English",

volume = "59",

pages = "5532--5534",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "19",

}

TY - JOUR

T1 - Total Synthesis of (‒)-Grayanotoxin III

AU - Kan, Toshiyuki

AU - Hosokawa, Seijiro

AU - Nara, Shinji

AU - Oikawa, Masato

AU - Ito, Shinya

AU - Matsuda, Fuyuhiko

AU - Shirahama, Haruhisa

PY - 1994/9/1

Y1 - 1994/9/1

N2 - Total synthesis of (‒)-grayanotoxin III (3), a unique tetracyclic diterpene isolated from the leaves of various plants of the family Ericaceae, has been successfully accomplished featuring the highly stereoselective cyclization reactions induced by SmI2.

AB - Total synthesis of (‒)-grayanotoxin III (3), a unique tetracyclic diterpene isolated from the leaves of various plants of the family Ericaceae, has been successfully accomplished featuring the highly stereoselective cyclization reactions induced by SmI2.

UR - http://www.scopus.com/inward/record.url?scp=0027959544&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0027959544&partnerID=8YFLogxK

U2 - 10.1021/jo00098a009

DO - 10.1021/jo00098a009

M3 - Letter

AN - SCOPUS:0027959544

SN - 0022-3263

VL - 59

SP - 5532

EP - 5534

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 19

ER -

Total Synthesis of (‒)-Grayanotoxin III

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this