Unprecedentedly fast DNA hydrolysis by the synergism of the cerium(IV)-praseodymium(III) and the cerium(IV)-neodymium(III) combinations

Naoya Takeda; Takamitsu Imai; Makoto Irisawa; Jun Sumaoka; Mono Yashiro; Hidemi Shigekawa; Makoto Komiyama

doi:10.1246/cl.1996.599

Unprecedentedly fast DNA hydrolysis by the synergism of the cerium(IV)-praseodymium(III) and the cerium(IV)-neodymium(III) combinations

Naoya Takeda, Takamitsu Imai, Makoto Irisawa, Jun Sumaoka, Mono Yashiro, Hidemi Shigekawa, Makoto Komiyama^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

The most active catalysts for DNA hydrolysis so far have been obtained by using the synergetic cooperation of the cerium(IV) ion with the praseodymium(III) ion. The pseudo first-order rate constant for the hydrolysis of thymidylyl(3'-5')thymidine by the 2:1 combination is 10 times as great as that by the cerium(IV) ion.

Original language	English
Pages (from-to)	599-600
Number of pages	2
Journal	Chemistry Letters
Issue number	8
DOIs	https://doi.org/10.1246/cl.1996.599
Publication status	Published - 1996
Externally published	Yes

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Chemistry(all)

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10.1246/cl.1996.599

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title = "Unprecedentedly fast DNA hydrolysis by the synergism of the cerium(IV)-praseodymium(III) and the cerium(IV)-neodymium(III) combinations",

abstract = "The most active catalysts for DNA hydrolysis so far have been obtained by using the synergetic cooperation of the cerium(IV) ion with the praseodymium(III) ion. The pseudo first-order rate constant for the hydrolysis of thymidylyl(3'-5')thymidine by the 2:1 combination is 10 times as great as that by the cerium(IV) ion.",

author = "Naoya Takeda and Takamitsu Imai and Makoto Irisawa and Jun Sumaoka and Mono Yashiro and Hidemi Shigekawa and Makoto Komiyama",

note = "Funding Information: This work was supported by two Swiss National Science Foundation grants (grant numbers 165956 for Lausanne, 166204 for Basel), the OPO Foundation, and the Isaac Dreyfus Foundation (Basel).",

year = "1996",

doi = "10.1246/cl.1996.599",

language = "English",

pages = "599--600",

journal = "Chemistry Letters",

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publisher = "Chemical Society of Japan",

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T1 - Unprecedentedly fast DNA hydrolysis by the synergism of the cerium(IV)-praseodymium(III) and the cerium(IV)-neodymium(III) combinations

AU - Takeda, Naoya

AU - Imai, Takamitsu

AU - Irisawa, Makoto

AU - Sumaoka, Jun

AU - Yashiro, Mono

AU - Shigekawa, Hidemi

AU - Komiyama, Makoto

N1 - Funding Information: This work was supported by two Swiss National Science Foundation grants (grant numbers 165956 for Lausanne, 166204 for Basel), the OPO Foundation, and the Isaac Dreyfus Foundation (Basel).

PY - 1996

Y1 - 1996

N2 - The most active catalysts for DNA hydrolysis so far have been obtained by using the synergetic cooperation of the cerium(IV) ion with the praseodymium(III) ion. The pseudo first-order rate constant for the hydrolysis of thymidylyl(3'-5')thymidine by the 2:1 combination is 10 times as great as that by the cerium(IV) ion.

AB - The most active catalysts for DNA hydrolysis so far have been obtained by using the synergetic cooperation of the cerium(IV) ion with the praseodymium(III) ion. The pseudo first-order rate constant for the hydrolysis of thymidylyl(3'-5')thymidine by the 2:1 combination is 10 times as great as that by the cerium(IV) ion.

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Unprecedentedly fast DNA hydrolysis by the synergism of the cerium(IV)-praseodymium(III) and the cerium(IV)-neodymium(III) combinations

Abstract

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