X-ray emission and photoelectron spectra of Pr0.5Sr0.5MnO3

E. Z. Kurmaev; M. A. Korotin; V. R. Galakhov; L. D. Finkelstein; E. I. Zabolotzky; N. N. Efremova; S. Stadler; D. L. Ederer; A. Moewes; S. Bartkowski; M. Neumann; J. Matsuno; T. Mizokawa; A. Fujimori; J. Mitchell

doi:10.1016/s0368-2048(98)00426-5

X-ray emission and photoelectron spectra of Pr_0.5Sr_0.5MnO₃

E. Z. Kurmaev^*, M. A. Korotin, V. R. Galakhov, L. D. Finkelstein, E. I. Zabolotzky, N. N. Efremova, S. Stadler, D. L. Ederer, A. Moewes, S. Bartkowski, M. Neumann, J. Matsuno, T. Mizokawa, A. Fujimori, J. Mitchell

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The results of measurements of X-ray photoelectron (XPS), X-ray emission (XES) and X-ray absorption spectra and LSDA band structure calculations of Pr_0.5Sr_0.5MnO₃ are presented. The excitation energy dependence of Mn L_2,3 and O K_α X-ray emission spectra of Pr_0.5Sr_0.5MnO₃ is measured using tunable synchrotron radiation. Comparing XPS and XES measurements and the LSDA band structure calculations, one concludes that the Mn 3d states are localized near the top of the valence band. Some differences in the Mn 3d-distribution in the upper part of the XPS valence band and Mn L₃ XES are due to spin selection rules.

Original language	English
Pages (from-to)	793-798
Number of pages	6
Journal	Journal of Electron Spectroscopy and Related Phenomena
Volume	101-103
DOIs	https://doi.org/10.1016/s0368-2048(98)00426-5
Publication status	Published - 1999
Externally published	Yes

Keywords

Electronic structure
Manganites
X-ray emission resonant spectra
X-ray photoelectron spectra

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Radiation
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry

Access to Document

10.1016/s0368-2048(98)00426-5

Cite this

Kurmaev, E. Z., Korotin, M. A., Galakhov, V. R., Finkelstein, L. D., Zabolotzky, E. I., Efremova, N. N., Stadler, S., Ederer, D. L., Moewes, A., Bartkowski, S., Neumann, M., Matsuno, J., Mizokawa, T., Fujimori, A., & Mitchell, J. (1999). X-ray emission and photoelectron spectra of Pr_0.5Sr_0.5MnO₃. Journal of Electron Spectroscopy and Related Phenomena, 101-103, 793-798. https://doi.org/10.1016/s0368-2048(98)00426-5

Kurmaev, EZ, Korotin, MA, Galakhov, VR, Finkelstein, LD, Zabolotzky, EI, Efremova, NN, Stadler, S, Ederer, DL, Moewes, A, Bartkowski, S, Neumann, M, Matsuno, J, Mizokawa, T, Fujimori, A & Mitchell, J 1999, 'X-ray emission and photoelectron spectra of Pr_0.5Sr_0.5MnO₃', Journal of Electron Spectroscopy and Related Phenomena, vol. 101-103, pp. 793-798. https://doi.org/10.1016/s0368-2048(98)00426-5

@article{a3758208cee647c7835c7552a7a664a4,

title = "X-ray emission and photoelectron spectra of Pr0.5Sr0.5MnO3",

abstract = "The results of measurements of X-ray photoelectron (XPS), X-ray emission (XES) and X-ray absorption spectra and LSDA band structure calculations of Pr0.5Sr0.5MnO3 are presented. The excitation energy dependence of Mn L2,3 and O Kα X-ray emission spectra of Pr0.5Sr0.5MnO3 is measured using tunable synchrotron radiation. Comparing XPS and XES measurements and the LSDA band structure calculations, one concludes that the Mn 3d states are localized near the top of the valence band. Some differences in the Mn 3d-distribution in the upper part of the XPS valence band and Mn L3 XES are due to spin selection rules.",

keywords = "Electronic structure, Manganites, X-ray emission resonant spectra, X-ray photoelectron spectra",

author = "Kurmaev, {E. Z.} and Korotin, {M. A.} and Galakhov, {V. R.} and Finkelstein, {L. D.} and Zabolotzky, {E. I.} and Efremova, {N. N.} and S. Stadler and Ederer, {D. L.} and A. Moewes and S. Bartkowski and M. Neumann and J. Matsuno and T. Mizokawa and A. Fujimori and J. Mitchell",

note = "Funding Information: This work was supported by the Russian State Program on Superconductivity (Project 95026), Russian Science Foundation for Fundamental Research (Projects N 98-02-17275 and 96-15-96598), NATO Linkage Grant (HTECH.LG 971222), the NSF Grants (No. DMR-901 7997 and No. DMR-9420425) and the DOE EPSCOR and Louisiana Education Quality Special Fund (Grant No. DOE-LEQSF (1993-95-03)). The work at the Advanced Light Source at Lawrence Berkeley National Laboratory was supported by US Department of Energy (Contract No. DE-AC03-76SF00098).",

year = "1999",

doi = "10.1016/s0368-2048(98)00426-5",

language = "English",

volume = "101-103",

pages = "793--798",

journal = "Journal of Electron Spectroscopy and Related Phenomena",

issn = "0368-2048",

publisher = "Elsevier",

}

TY - JOUR

T1 - X-ray emission and photoelectron spectra of Pr0.5Sr0.5MnO3

AU - Kurmaev, E. Z.

AU - Korotin, M. A.

AU - Galakhov, V. R.

AU - Finkelstein, L. D.

AU - Zabolotzky, E. I.

AU - Efremova, N. N.

AU - Stadler, S.

AU - Ederer, D. L.

AU - Moewes, A.

AU - Bartkowski, S.

AU - Neumann, M.

AU - Matsuno, J.

AU - Mizokawa, T.

AU - Fujimori, A.

AU - Mitchell, J.

N1 - Funding Information: This work was supported by the Russian State Program on Superconductivity (Project 95026), Russian Science Foundation for Fundamental Research (Projects N 98-02-17275 and 96-15-96598), NATO Linkage Grant (HTECH.LG 971222), the NSF Grants (No. DMR-901 7997 and No. DMR-9420425) and the DOE EPSCOR and Louisiana Education Quality Special Fund (Grant No. DOE-LEQSF (1993-95-03)). The work at the Advanced Light Source at Lawrence Berkeley National Laboratory was supported by US Department of Energy (Contract No. DE-AC03-76SF00098).

PY - 1999

Y1 - 1999

N2 - The results of measurements of X-ray photoelectron (XPS), X-ray emission (XES) and X-ray absorption spectra and LSDA band structure calculations of Pr0.5Sr0.5MnO3 are presented. The excitation energy dependence of Mn L2,3 and O Kα X-ray emission spectra of Pr0.5Sr0.5MnO3 is measured using tunable synchrotron radiation. Comparing XPS and XES measurements and the LSDA band structure calculations, one concludes that the Mn 3d states are localized near the top of the valence band. Some differences in the Mn 3d-distribution in the upper part of the XPS valence band and Mn L3 XES are due to spin selection rules.

AB - The results of measurements of X-ray photoelectron (XPS), X-ray emission (XES) and X-ray absorption spectra and LSDA band structure calculations of Pr0.5Sr0.5MnO3 are presented. The excitation energy dependence of Mn L2,3 and O Kα X-ray emission spectra of Pr0.5Sr0.5MnO3 is measured using tunable synchrotron radiation. Comparing XPS and XES measurements and the LSDA band structure calculations, one concludes that the Mn 3d states are localized near the top of the valence band. Some differences in the Mn 3d-distribution in the upper part of the XPS valence band and Mn L3 XES are due to spin selection rules.

KW - Electronic structure

KW - Manganites

KW - X-ray emission resonant spectra

KW - X-ray photoelectron spectra

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DO - 10.1016/s0368-2048(98)00426-5

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AN - SCOPUS:30744457059

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VL - 101-103

SP - 793

EP - 798

JO - Journal of Electron Spectroscopy and Related Phenomena

JF - Journal of Electron Spectroscopy and Related Phenomena

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