3-Dithiolthione-substituted polythiophene and its redox activities

Ichiro Takemura; Tomokazu Iwasaki; Shinji Takeoka; Hiroyuki Nishide

doi:10.1246/cl.2004.1482

3-Dithiolthione-substituted polythiophene and its redox activities

Ichiro Takemura, Tomokazu Iwasaki, Shinji Takeoka, Hiroyuki Nishide^*

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

1 被引用数 (Scopus)

抄録

We synthesized 3-dithiolthione-substituted polythiophene, poly[3-(1′,2′-dithiol-3′-thione-4′-yl)thiophene], by cyclization reaction of poly[3-bis(methoxycaronyl)methyl thiophene]. Its redox behavior and electronic states showed that the oxidation of the polythiophene followed the oxidation of the dithiolthione ring to the radical cation of the dithiolthione ring.

本文言語	English
ページ（範囲）	1482-1483
ページ数	2
ジャーナル	Chemistry Letters
巻	33
号	11
DOI	https://doi.org/10.1246/cl.2004.1482
出版ステータス	Published - 2004 11月 5

ASJC Scopus subject areas

化学 (全般)

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10.1246/cl.2004.1482

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abstract = "We synthesized 3-dithiolthione-substituted polythiophene, poly[3-(1′,2′-dithiol-3′-thione-4′-yl)thiophene], by cyclization reaction of poly[3-bis(methoxycaronyl)methyl thiophene]. Its redox behavior and electronic states showed that the oxidation of the polythiophene followed the oxidation of the dithiolthione ring to the radical cation of the dithiolthione ring.",

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AU - Iwasaki, Tomokazu

AU - Takeoka, Shinji

AU - Nishide, Hiroyuki

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N2 - We synthesized 3-dithiolthione-substituted polythiophene, poly[3-(1′,2′-dithiol-3′-thione-4′-yl)thiophene], by cyclization reaction of poly[3-bis(methoxycaronyl)methyl thiophene]. Its redox behavior and electronic states showed that the oxidation of the polythiophene followed the oxidation of the dithiolthione ring to the radical cation of the dithiolthione ring.

AB - We synthesized 3-dithiolthione-substituted polythiophene, poly[3-(1′,2′-dithiol-3′-thione-4′-yl)thiophene], by cyclization reaction of poly[3-bis(methoxycaronyl)methyl thiophene]. Its redox behavior and electronic states showed that the oxidation of the polythiophene followed the oxidation of the dithiolthione ring to the radical cation of the dithiolthione ring.

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3-Dithiolthione-substituted polythiophene and its redox activities

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