A cyclic tetramer of [Ag(1,4,7-trithiacyclononane)]+, cyclo-tetrakis(μ-1,4,7-trithiacyclononane-κ3S1,S 4,S7:κS1)tetrasilver(I) tetrakis(trifluoromethanesulfonate) nitromethane disolvate

Tadashi Yamaguchi; Fumie Yamazaki; Tasuku Ito

doi:10.1107/S0108270102001075

A cyclic tetramer of [Ag(1,4,7-trithiacyclononane)]⁺, cyclo-tetrakis(μ-1,4,7-trithiacyclononane-κ³S¹,S ⁴,S⁷:κS¹)tetrasilver(I) tetrakis(trifluoromethanesulfonate) nitromethane disolvate

Tadashi Yamaguchi^*, Fumie Yamazaki, Tasuku Ito

^*この研究の対応する著者

研究成果: Article › 査読

13 被引用数 (Scopus)

抄録

(1,4,7-Trithiacyclononane) silver trifluoromethanesulfonate crystallizes in a tetrameric form from nitromethane, to give the title compound, [Ag₄(C₆H₁₂S₃)₄](CF₃SO₃)₄·2CH₃NO₂. The complex cation consists of four [AgL]⁺ units (L is 1,4,7-trithiacyclononane), with four Ag-S-Ag bridges forming a cyclic tetramer. The almost planar Ag₄S₄ ring takes an octagonal form.

本文言語	English
ページ（範囲）	m213-m214
ジャーナル	Acta Crystallographica Section C: Crystal Structure Communications
巻	58
号	4
DOI	https://doi.org/10.1107/S0108270102001075
出版ステータス	Published - 2002 4月
外部発表	はい

ASJC Scopus subject areas

生化学、遺伝学、分子生物学（全般）

文献へのアクセス

10.1107/S0108270102001075

他のファイルとリンク

フィンガープリント

「A cyclic tetramer of [Ag(1,4,7-trithiacyclononane)]⁺, cyclo-tetrakis(μ-1,4,7-trithiacyclononane-κ³S¹,S ⁴,S⁷:κS¹)tetrasilver(I) tetrakis(trifluoromethanesulfonate) nitromethane disolvate」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

A cyclic tetramer of [Ag(1,4,7-trithiacyclononane)]⁺, cyclo-tetrakis(μ-1,4,7-trithiacyclononane-κ³S¹,S ⁴,S⁷:κS¹)tetrasilver(I) tetrakis(trifluoromethanesulfonate) nitromethane disolvate. / Yamaguchi, Tadashi; Yamazaki, Fumie; Ito, Tasuku.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 58, No. 4, 04.2002, p. m213-m214.

研究成果: Article › 査読

Yamaguchi, T, Yamazaki, F & Ito, T 2002, 'A cyclic tetramer of [Ag(1,4,7-trithiacyclononane)]⁺, cyclo-tetrakis(μ-1,4,7-trithiacyclononane-κ³S¹,S ⁴,S⁷:κS¹)tetrasilver(I) tetrakis(trifluoromethanesulfonate) nitromethane disolvate', Acta Crystallographica Section C: Crystal Structure Communications, vol. 58, no. 4, pp. m213-m214. https://doi.org/10.1107/S0108270102001075

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abstract = "(1,4,7-Trithiacyclononane) silver trifluoromethanesulfonate crystallizes in a tetrameric form from nitromethane, to give the title compound, [Ag4(C6H12S3)4](CF3 SO3)4·2CH3NO2. The complex cation consists of four [AgL]+ units (L is 1,4,7-trithiacyclononane), with four Ag-S-Ag bridges forming a cyclic tetramer. The almost planar Ag4S4 ring takes an octagonal form.",

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