抄録
A new asymmetric total synthesis of (-)-malyngolide is described. This synthesis is based on the originally developed catalytic asymmetric IMCP reaction; that is, α-diazo-β-keto sulfone (13) was successfully converted to cyclopropane (12) in 92% yield with excellent enantioselectivity (97% ee), and cyclopropane (12) was successfully converted to (-)-malyngolide.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 61-68 |
| ページ数 | 8 |
| ジャーナル | Heterocycles |
| 巻 | 66 |
| 号 | 1 |
| DOI | |
| 出版ステータス | Published - 2005 12月 31 |
ASJC Scopus subject areas
- 分析化学
- 薬理学
- 有機化学