A new one-pot method for α,α-diallylation of ketones based on the palladium-catalyzed reaction of allylic carbonates and allyl β-keto carboxylates under neutral conditions

Isao Shimizu; Yukihiro Ohashi; Jiro Tsuji

doi:10.1016/S0040-4039(00)94297-7

A new one-pot method for α,α-diallylation of ketones based on the palladium-catalyzed reaction of allylic carbonates and allyl β-keto carboxylates under neutral conditions

Isao Shimizu^*, Yukihiro Ohashi, Jiro Tsuji

^*この研究の対応する著者

研究成果: Article › 査読

9 被引用数 (Scopus)

抄録

A new method for α,α-diallylation of ketones catalyzed by palladium-phosphine complexes under neutral conditions has been developed. Allylation of β-keto carboxylates with allylic carbonates, followed by the decarboxylation-allylation as a one-pot reaction affords diallylated ketones in good yields.

本文言語	English
ページ（範囲）	3865-3868
ページ数	4
ジャーナル	Tetrahedron Letters
巻	24
号	36
DOI	https://doi.org/10.1016/S0040-4039(00)94297-7
出版ステータス	Published - 1983

ASJC Scopus subject areas

生化学
有機化学
創薬

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10.1016/S0040-4039(00)94297-7

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AU - Tsuji, Jiro

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