A new synthetic route to poly(seleno-1,4-phenylene) from selenoanisole

Kenichi Oyaizu; Youjiro Ikai; Eishun Tsuchida

doi:10.1081/MA-100105965

A new synthetic route to poly(seleno-1,4-phenylene) from selenoanisole

Kenichi Oyaizu, Youjiro Ikai, Eishun Tsuchida^*

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

2 被引用数 (Scopus)

抄録

A method was developed to prepare poly(thio-1,4-phenylene) (PPS) from prepolymers containing alkylsulfoniophenylene units by dealkylation of sulfonium moities using nucleophilic reagents. Selenoanisole was quantitatively obtained by the condensation of selenophenol with methyl iodide in H₂O in the presence of NaOH. Aryl selenides were produced by Swern condensation of alkyl selenoxides followed by the nucleophilic dealkylation of the resulting selenonium salts.

本文言語	English
ページ（範囲）	1049-1057
ページ数	9
ジャーナル	Journal of Macromolecular Science - Pure and Applied Chemistry
巻	38 A
号	10
DOI	https://doi.org/10.1081/MA-100105965
出版ステータス	Published - 2001

ASJC Scopus subject areas

セラミックおよび複合材料
化学 (全般)
ポリマーおよびプラスチック
材料化学

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10.1081/MA-100105965

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title = "A new synthetic route to poly(seleno-1,4-phenylene) from selenoanisole",

abstract = "A method was developed to prepare poly(thio-1,4-phenylene) (PPS) from prepolymers containing alkylsulfoniophenylene units by dealkylation of sulfonium moities using nucleophilic reagents. Selenoanisole was quantitatively obtained by the condensation of selenophenol with methyl iodide in H2O in the presence of NaOH. Aryl selenides were produced by Swern condensation of alkyl selenoxides followed by the nucleophilic dealkylation of the resulting selenonium salts.",

keywords = "Aryl selenide, Aryl selenoxide, Poly(arylene selenide), Polycondensation, Polyelectrolyte",

author = "Kenichi Oyaizu and Youjiro Ikai and Eishun Tsuchida",

note = "Funding Information: This work was partially supported by a Grant-in-Aid for Scientific Research (No. 11650878) from the Ministry of Education, Science, Sports and Culture, Japan. E. T. is a CREST Investigator for the Japan Science and Technology Corporation (JST).",

year = "2001",

doi = "10.1081/MA-100105965",

language = "English",

volume = "38 A",

pages = "1049--1057",

journal = "Journal of Macromolecular Science - Pure and Applied Chemistry",

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T1 - A new synthetic route to poly(seleno-1,4-phenylene) from selenoanisole

AU - Oyaizu, Kenichi

AU - Ikai, Youjiro

AU - Tsuchida, Eishun

N1 - Funding Information: This work was partially supported by a Grant-in-Aid for Scientific Research (No. 11650878) from the Ministry of Education, Science, Sports and Culture, Japan. E. T. is a CREST Investigator for the Japan Science and Technology Corporation (JST).

PY - 2001

Y1 - 2001

N2 - A method was developed to prepare poly(thio-1,4-phenylene) (PPS) from prepolymers containing alkylsulfoniophenylene units by dealkylation of sulfonium moities using nucleophilic reagents. Selenoanisole was quantitatively obtained by the condensation of selenophenol with methyl iodide in H2O in the presence of NaOH. Aryl selenides were produced by Swern condensation of alkyl selenoxides followed by the nucleophilic dealkylation of the resulting selenonium salts.

AB - A method was developed to prepare poly(thio-1,4-phenylene) (PPS) from prepolymers containing alkylsulfoniophenylene units by dealkylation of sulfonium moities using nucleophilic reagents. Selenoanisole was quantitatively obtained by the condensation of selenophenol with methyl iodide in H2O in the presence of NaOH. Aryl selenides were produced by Swern condensation of alkyl selenoxides followed by the nucleophilic dealkylation of the resulting selenonium salts.

KW - Aryl selenide

KW - Aryl selenoxide

KW - Poly(arylene selenide)

KW - Polycondensation

KW - Polyelectrolyte

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DO - 10.1081/MA-100105965

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JO - Journal of Macromolecular Science - Pure and Applied Chemistry

JF - Journal of Macromolecular Science - Pure and Applied Chemistry

IS - 10

ER -

A new synthetic route to poly(seleno-1,4-phenylene) from selenoanisole

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