A non-heme iron(III) complex with porphyrin-like properties that catalyzes asymmetric epoxidation

Takashi Niwa; Masahisa Nakada

doi:10.1021/ja304219s

A non-heme iron(III) complex with porphyrin-like properties that catalyzes asymmetric epoxidation

Takashi Niwa^*, Masahisa Nakada

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

82 被引用数 (Scopus)

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In this report, we describe an iron(III) complex containing a carbazole-based tridentate ligand that catalyzes highly enantioselective asymmetric epoxidation of (E)-alkenes at room temperature. The non-heme iron(III) complex has a five-coordinated trigonal-bipyramidal structure, and its two-electron oxidized state has the similar electronic structure as that of iron porphyrins.

本文言語	English
ページ（範囲）	13538-13541
ページ数	4
ジャーナル	Journal of the American Chemical Society
巻	134
号	33
DOI	https://doi.org/10.1021/ja304219s
出版ステータス	Published - 2012 8月 22

ASJC Scopus subject areas

触媒
化学 (全般)
生化学
コロイド化学および表面化学

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AB - In this report, we describe an iron(III) complex containing a carbazole-based tridentate ligand that catalyzes highly enantioselective asymmetric epoxidation of (E)-alkenes at room temperature. The non-heme iron(III) complex has a five-coordinated trigonal-bipyramidal structure, and its two-electron oxidized state has the similar electronic structure as that of iron porphyrins.

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A non-heme iron(III) complex with porphyrin-like properties that catalyzes asymmetric epoxidation

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