TY - JOUR
T1 - A rock-salt-like lattice structure consisting of monocationic and monoanionic AuIAgICuII supramolecular cages of D-penicillaminate
AU - Toyota, Atsushi
AU - Yamaguchi, Tadashi
AU - Igashira-Kamiyama, Asako
AU - Kawamoto, Tatsuya
AU - Konno, Takumi
PY - 2005/2/4
Y1 - 2005/2/4
N2 - All three coinage metals are present in the supramolecular compound created from D-penicillamine (D-H2pen) by stepwise reaction with Au I, AgI, and CuII in the presence of Cl -. In this compound, 20-nuclear monocationic [Au6Ag 8Cu6Cl-(H2O)5(D-pen) 12]+ and 21-nuclear monoanionic [Au6Ag 9Cu6Cl4(H2O)6(D-pen) 12]- (see picture) supramolecular cages, each of which accommodates a Cl- ion (green), are linked so as to form a giant rock-salt-like lattice structure.
AB - All three coinage metals are present in the supramolecular compound created from D-penicillamine (D-H2pen) by stepwise reaction with Au I, AgI, and CuII in the presence of Cl -. In this compound, 20-nuclear monocationic [Au6Ag 8Cu6Cl-(H2O)5(D-pen) 12]+ and 21-nuclear monoanionic [Au6Ag 9Cu6Cl4(H2O)6(D-pen) 12]- (see picture) supramolecular cages, each of which accommodates a Cl- ion (green), are linked so as to form a giant rock-salt-like lattice structure.
KW - Aggregation
KW - Cage compounds
KW - S ligands
KW - Supramolecular chemistry
KW - Transition metals
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U2 - 10.1002/anie.200462205
DO - 10.1002/anie.200462205
M3 - Article
C2 - 15630706
AN - SCOPUS:15444377411
SN - 1433-7851
VL - 44
SP - 1088
EP - 1092
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 7
ER -