A versatile route to polythiophenes with functional pendant groups using alkyne chemistry

Xiao Huang; Li Yang; Rikard Emanuelsson; Jonas Bergquist; Maria Strømme; Martin Sjödin; Adolf Gogoll

doi:10.3762/bjoc.12.265

A versatile route to polythiophenes with functional pendant groups using alkyne chemistry

Xiao Huang^*, Li Yang, Rikard Emanuelsson, Jonas Bergquist, Maria Strømme, Martin Sjödin, Adolf Gogoll

^*この研究の対応する著者

研究成果: Article › 査読

12 被引用数 (Scopus)

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A new versatile polythiophene building block, 3-(3,4-ethylenedioxythiophene)prop-1-yne (pyEDOT) (3), is prepared from glycidol in four steps in 28% overall yield. pyEDOT features an ethynyl group on its ethylenedioxy bridge, allowing further functionalization by alkyne chemistry. Its usefulness is demonstrated by a series of functionalized polythiophene derivatives that were obtained by pre- and post-electropolymerization transformations, provided by the synthetic ease of the Sonogashira coupling and click chemistry.

本文言語	English
ページ（範囲）	2682-2688
ページ数	7
ジャーナル	Beilstein Journal of Organic Chemistry
巻	12
DOI	https://doi.org/10.3762/bjoc.12.265
出版ステータス	Published - 2016 12月 9
外部発表	はい

ASJC Scopus subject areas

有機化学

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10.3762/bjoc.12.265

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abstract = "A new versatile polythiophene building block, 3-(3,4-ethylenedioxythiophene)prop-1-yne (pyEDOT) (3), is prepared from glycidol in four steps in 28% overall yield. pyEDOT features an ethynyl group on its ethylenedioxy bridge, allowing further functionalization by alkyne chemistry. Its usefulness is demonstrated by a series of functionalized polythiophene derivatives that were obtained by pre- and post-electropolymerization transformations, provided by the synthetic ease of the Sonogashira coupling and click chemistry.",

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author = "Xiao Huang and Li Yang and Rikard Emanuelsson and Jonas Bergquist and Maria Str{\o}mme and Martin Sj{\"o}din and Adolf Gogoll",

year = "2016",

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T1 - A versatile route to polythiophenes with functional pendant groups using alkyne chemistry

AU - Huang, Xiao

AU - Yang, Li

AU - Emanuelsson, Rikard

AU - Bergquist, Jonas

AU - Strømme, Maria

AU - Sjödin, Martin

AU - Gogoll, Adolf

PY - 2016/12/9

Y1 - 2016/12/9

N2 - A new versatile polythiophene building block, 3-(3,4-ethylenedioxythiophene)prop-1-yne (pyEDOT) (3), is prepared from glycidol in four steps in 28% overall yield. pyEDOT features an ethynyl group on its ethylenedioxy bridge, allowing further functionalization by alkyne chemistry. Its usefulness is demonstrated by a series of functionalized polythiophene derivatives that were obtained by pre- and post-electropolymerization transformations, provided by the synthetic ease of the Sonogashira coupling and click chemistry.

AB - A new versatile polythiophene building block, 3-(3,4-ethylenedioxythiophene)prop-1-yne (pyEDOT) (3), is prepared from glycidol in four steps in 28% overall yield. pyEDOT features an ethynyl group on its ethylenedioxy bridge, allowing further functionalization by alkyne chemistry. Its usefulness is demonstrated by a series of functionalized polythiophene derivatives that were obtained by pre- and post-electropolymerization transformations, provided by the synthetic ease of the Sonogashira coupling and click chemistry.

KW - Electropolymerization

KW - Functional polymers

KW - Polythiophene

KW - Sonogashira coupling

KW - Thiophene

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JO - Beilstein Journal of Organic Chemistry

JF - Beilstein Journal of Organic Chemistry

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A versatile route to polythiophenes with functional pendant groups using alkyne chemistry

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