Alkynyl bridged cyclometalated Ir2M2 clusters: Impact of the heterometal in the photo- and electro-luminescence properties

Julio Fernández-Cestau; Nora Giménez; Elena Lalinde; Patricia Montaño; M. Teresa Moreno; Sergio Sánchez; Michael D. Weber; Rubén D. Costa

doi:10.1039/c5dt04027b

Alkynyl bridged cyclometalated Ir₂M₂ clusters: Impact of the heterometal in the photo- and electro-luminescence properties

Julio Fernández-Cestau, Nora Giménez, Elena Lalinde^*, Patricia Montaño, M. Teresa Moreno, Sergio Sánchez, Michael D. Weber, Rubén D. Costa

^*この研究の対応する著者

研究成果: Article › 査読

9 被引用数 (Scopus)

抄録

We report two unprecedent alkynyl bridging cyclometalated clusters [Ir₂M₂(ppy)₄(μ-CCC₆H₄-OMe₃)₄] where M is Ag (2) and Cu (3), which display distinctive luminescence properties. While 2 features a green phosphorescence/electroluminescence nature located at the ppy ligands (³LC), 3 shows an orange emission confined to the metals and alkynyl groups having a mixed ³L′C/³L′MCT/³MMCT (L′ = alkynyl) nature.

本文言語	English
ページ（範囲）	3251-3255
ページ数	5
ジャーナル	Dalton Transactions
巻	45
号	8
DOI	https://doi.org/10.1039/c5dt04027b
出版ステータス	Published - 2016
外部発表	はい

ASJC Scopus subject areas

無機化学

文献へのアクセス

10.1039/c5dt04027b

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引用スタイル

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abstract = "We report two unprecedent alkynyl bridging cyclometalated clusters [Ir2M2(ppy)4(μ-CCC6H4-OMe3)4] where M is Ag (2) and Cu (3), which display distinctive luminescence properties. While 2 features a green phosphorescence/electroluminescence nature located at the ppy ligands (3LC), 3 shows an orange emission confined to the metals and alkynyl groups having a mixed 3L′C/3L′MCT/3MMCT (L′ = alkynyl) nature.",

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AU - Moreno, M. Teresa

AU - Sánchez, Sergio

AU - Weber, Michael D.

AU - Costa, Rubén D.

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