@article{cefa5798bed04dbcb24a12d64ea37caf,
title = "Anomalous Potential Shifts of Redox-active Molecules in Highly Concentrated Electrolytes",
abstract = "Redox potentials of various redox-active molecules were examined in highly concentrated electrolytes. At the high concentration regions, the shifts were significantly larger than the conventional trend («0.059 V/dec) expected from the salt concentration terms in the Nernst equation. Decreased activity of the molecular salts was considered to explain the shift. The dramatic potential changes will play essential roles in designing molecule-based energy devices.",
keywords = "Organic battery, Organic redox-active materials, Redox potential",
author = "Kan Hatakeyama-Sato and Satoshi Matsumoto and Ikuma Aida and Kenichi Oyaizu",
note = "Funding Information: This work was partially supported by Grants-in-Aid for Scientific Research (Nos. 17H03072, 18K19120, 18H05515, 20H05298, 21H02017, and 19K15638) from MEXT, Japan. The work was also partially supported by the Research Institute for Science and Engineering, Waseda University. Publisher Copyright: {\textcopyright} 2021 The Chemical Society of Japan",
year = "2021",
month = jul,
doi = "10.1246/cl.210124",
language = "English",
volume = "50",
pages = "1375--1377",
journal = "Chemistry Letters",
issn = "0366-7022",
publisher = "Chemical Society of Japan",
number = "7",
}