TY - GEN
T1 - Charge-transporting property of poly(l,3-phenylenevinylene) containing a nitroxide-substituted phenylamine moiety
AU - Kato, Fumiaki
AU - Kurata, Takashi
AU - Nishide, Hiroyuki
AU - Kido, Junji
PY - 2005
Y1 - 2005
N2 - A new hole-transporting polyradical, poly(4-(N-t-butyl-N-oxyamino) triphenylamine-alt-5-hexyloxy-1,3-phenylenevinylene), was synthesized by Wittig reaction of 4-{N-i-butyl-N-(t-butyldimethylsilyl)oxy}amine-substituted bisformyltriphenylamine and l,3-bis{(triphenylphospho)methyl}benzene dibromide, followed by deprotection and oxidation. Electrochemical or magnetic measurements revealed the electronic structure and charge transporting property of the polyradical.
AB - A new hole-transporting polyradical, poly(4-(N-t-butyl-N-oxyamino) triphenylamine-alt-5-hexyloxy-1,3-phenylenevinylene), was synthesized by Wittig reaction of 4-{N-i-butyl-N-(t-butyldimethylsilyl)oxy}amine-substituted bisformyltriphenylamine and l,3-bis{(triphenylphospho)methyl}benzene dibromide, followed by deprotection and oxidation. Electrochemical or magnetic measurements revealed the electronic structure and charge transporting property of the polyradical.
KW - Nitroxide
KW - PolyradicalRedox property
KW - Wittig reaction
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M3 - Conference contribution
AN - SCOPUS:33645644675
VL - 54
SP - 4107
BT - Polymer Preprints, Japan
T2 - 54th SPSJ Symposium on Macromolecules
Y2 - 20 September 2005 through 22 September 2005
ER -