COMPLEXATION OF TERBIUM ION WITH THE COPOLYMER OF ACRYLIC ACID AND ACRYLAMIDE GRAFTED ONTO POLYETHYLENE.

Hideto Akiba; Hiroyuki Nishide; Eishun Tsuchida; Hideki Omichi; Jiro Okamoto

COMPLEXATION OF TERBIUM ION WITH THE COPOLYMER OF ACRYLIC ACID AND ACRYLAMIDE GRAFTED ONTO POLYETHYLENE.

Hideto Akiba^*, Hiroyuki Nishide, Eishun Tsuchida, Hideki Omichi, Jiro Okamoto

^*この研究の対応する著者

理工学術院総合研究所

研究成果: Article › 査読

4 被引用数 (Scopus)

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Acrylic acid (AA) and acrylamide (AAm) were graft copolymerized onto polyethylene powder by the preirradiation method. The PE powder grafted with both AA and AAm (PE-g-(AA-co-AAm)) rapidly adsorbed Tb ion with an efficiency higher than did PE powder grafted with AA (PE-g-AA). The complex formationn constant of Tb ion with PE-g-(AA-co-AAm) was larger than that with PE-g-AA because of the introduction of the acrylamide part decreased the steric hindrance for complexation between Tb and the carboxyl group of the graft chains.

本文言語	English
ページ（範囲）	1125-1135
ページ数	11
ジャーナル	Journal of macromolecular science. Chemistry
巻	A23
号	9
出版ステータス	Published - 1986 9月

ASJC Scopus subject areas

工学（全般）

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title = "COMPLEXATION OF TERBIUM ION WITH THE COPOLYMER OF ACRYLIC ACID AND ACRYLAMIDE GRAFTED ONTO POLYETHYLENE.",

abstract = "Acrylic acid (AA) and acrylamide (AAm) were graft copolymerized onto polyethylene powder by the preirradiation method. The PE powder grafted with both AA and AAm (PE-g-(AA-co-AAm)) rapidly adsorbed Tb ion with an efficiency higher than did PE powder grafted with AA (PE-g-AA). The complex formationn constant of Tb ion with PE-g-(AA-co-AAm) was larger than that with PE-g-AA because of the introduction of the acrylamide part decreased the steric hindrance for complexation between Tb and the carboxyl group of the graft chains.",

author = "Hideto Akiba and Hiroyuki Nishide and Eishun Tsuchida and Hideki Omichi and Jiro Okamoto",

year = "1986",

month = sep,

language = "English",

volume = "A23",

pages = "1125--1135",

journal = "Journal of macromolecular science. Chemistry",

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T1 - COMPLEXATION OF TERBIUM ION WITH THE COPOLYMER OF ACRYLIC ACID AND ACRYLAMIDE GRAFTED ONTO POLYETHYLENE.

AU - Akiba, Hideto

AU - Nishide, Hiroyuki

AU - Tsuchida, Eishun

AU - Omichi, Hideki

AU - Okamoto, Jiro

PY - 1986/9

Y1 - 1986/9

N2 - Acrylic acid (AA) and acrylamide (AAm) were graft copolymerized onto polyethylene powder by the preirradiation method. The PE powder grafted with both AA and AAm (PE-g-(AA-co-AAm)) rapidly adsorbed Tb ion with an efficiency higher than did PE powder grafted with AA (PE-g-AA). The complex formationn constant of Tb ion with PE-g-(AA-co-AAm) was larger than that with PE-g-AA because of the introduction of the acrylamide part decreased the steric hindrance for complexation between Tb and the carboxyl group of the graft chains.

AB - Acrylic acid (AA) and acrylamide (AAm) were graft copolymerized onto polyethylene powder by the preirradiation method. The PE powder grafted with both AA and AAm (PE-g-(AA-co-AAm)) rapidly adsorbed Tb ion with an efficiency higher than did PE powder grafted with AA (PE-g-AA). The complex formationn constant of Tb ion with PE-g-(AA-co-AAm) was larger than that with PE-g-AA because of the introduction of the acrylamide part decreased the steric hindrance for complexation between Tb and the carboxyl group of the graft chains.

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JO - Journal of macromolecular science. Chemistry

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COMPLEXATION OF TERBIUM ION WITH THE COPOLYMER OF ACRYLIC ACID AND ACRYLAMIDE GRAFTED ONTO POLYETHYLENE.

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