Crystal structure and physical properties of BEDT-TTF (bis(ethylenedithio) tetrathiafulvalene) salt coupled with a photo-sensitive transition metal complex

Masashi Ohkubo; Tokutaro Komatsu; Nobuyuki Matsushita; Norimichi Kojima; Gunzi Saito

doi:10.1080/10587250210746

Crystal structure and physical properties of BEDT-TTF (bis(ethylenedithio) tetrathiafulvalene) salt coupled with a photo-sensitive transition metal complex

Masashi Ohkubo^*, Tokutaro Komatsu, Nobuyuki Matsushita, Norimichi Kojima, Gunzi Saito

^*この研究の対応する著者

研究成果: Conference article › 査読

1 被引用数 (Scopus)

抄録

A new salt of BEDT-TTF with photo-sensitive transition metal complex [RuCl₅(NO)]^2- has been synthesized. The crystal structure was determined and attributed to the κ -type salt. Although calculated band structure shows two dimensional Fermi surfaces and predicts a metallic behavior, the resistivity shows semiconducting temperature dependence up to 6 kbar. Both the ESR signals of BEDT-TTF⁺ and NO exhibited a photo-induced effect.

本文言語	English
ページ（範囲）	147-152
ページ数	6
ジャーナル	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
巻	376
DOI	https://doi.org/10.1080/10587250210746
出版ステータス	Published - 2002
外部発表	はい
イベント	Proceedings of the Interdisciplinary Symposium on Multifunctionality of Inorganic , Organic, and Their Hybrid Solids - Honolulu, HI, United States 継続期間: 2000 12月 15 → 2000 12月 18

ASJC Scopus subject areas

凝縮系物理学

文献へのアクセス

10.1080/10587250210746

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引用スタイル

Ohkubo, M., Komatsu, T., Matsushita, N., Kojima, N., & Saito, G. (2002). Crystal structure and physical properties of BEDT-TTF (bis(ethylenedithio) tetrathiafulvalene) salt coupled with a photo-sensitive transition metal complex. Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 376, 147-152. https://doi.org/10.1080/10587250210746

Crystal structure and physical properties of BEDT-TTF (bis(ethylenedithio) tetrathiafulvalene) salt coupled with a photo-sensitive transition metal complex. / Ohkubo, Masashi; Komatsu, Tokutaro; Matsushita, Nobuyuki その他.
In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 376, 2002, p. 147-152.

研究成果: Conference article › 査読

Ohkubo, M, Komatsu, T, Matsushita, N, Kojima, N & Saito, G 2002, 'Crystal structure and physical properties of BEDT-TTF (bis(ethylenedithio) tetrathiafulvalene) salt coupled with a photo-sensitive transition metal complex', Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, vol. 376, pp. 147-152. https://doi.org/10.1080/10587250210746

Ohkubo, Masashi ; Komatsu, Tokutaro ; Matsushita, Nobuyuki その他. / Crystal structure and physical properties of BEDT-TTF (bis(ethylenedithio) tetrathiafulvalene) salt coupled with a photo-sensitive transition metal complex. In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals. 2002 ; Vol. 376. pp. 147-152.

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abstract = "A new salt of BEDT-TTF with photo-sensitive transition metal complex [RuCl5(NO)]2- has been synthesized. The crystal structure was determined and attributed to the κ -type salt. Although calculated band structure shows two dimensional Fermi surfaces and predicts a metallic behavior, the resistivity shows semiconducting temperature dependence up to 6 kbar. Both the ESR signals of BEDT-TTF+ and NO exhibited a photo-induced effect.",

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AU - Kojima, Norimichi

AU - Saito, Gunzi

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AB - A new salt of BEDT-TTF with photo-sensitive transition metal complex [RuCl5(NO)]2- has been synthesized. The crystal structure was determined and attributed to the κ -type salt. Although calculated band structure shows two dimensional Fermi surfaces and predicts a metallic behavior, the resistivity shows semiconducting temperature dependence up to 6 kbar. Both the ESR signals of BEDT-TTF+ and NO exhibited a photo-induced effect.

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