A new salt of BEDT-TTF with photo-sensitive transition metal complex [RuCl5(NO)]2- has been synthesized. The crystal structure was determined and attributed to the κ -type salt. Although calculated band structure shows two dimensional Fermi surfaces and predicts a metallic behavior, the resistivity shows semiconducting temperature dependence up to 6 kbar. Both the ESR signals of BEDT-TTF+ and NO exhibited a photo-induced effect.
|Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
|Published - 2002
|Proceedings of the Interdisciplinary Symposium on Multifunctionality of Inorganic , Organic, and Their Hybrid Solids - Honolulu, HI, United States
継続期間: 2000 12月 15 → 2000 12月 18
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