TY - JOUR
T1 - Crystal structure of [5-bromo-2-(pyridin-2-yl-κN)phenyl-κC 1](pentane-2,4-dionato-κ 2 O,O′)platinum(II)
AU - Fukuda, Keito
AU - Sugaya, Tomoaki
AU - Ishihara, Koji
N1 - Publisher Copyright:
© 2015.
PY - 2015
Y1 - 2015
N2 - The title cyclometalated platinum(II) complex with 2-(4-bromophenyl)pyridinato and acetylacetonato ligands, [Pt(C11H7BrN)(C5H7O2)], consists of two crystallographically non-equivalent dimers, each stacked by π-π interactions with distances of ≃ 3.4Å. In both dimers, the platinum(II) complexes are arranged antiparallel to each other. Each complex exhibits a slightly distorted square-planar coordination environment around the central Pt(II) atom. The dihedral angles between two chelate rings including the PtII atom in these complexes are 0.08(12) and 1.54(9)°.
AB - The title cyclometalated platinum(II) complex with 2-(4-bromophenyl)pyridinato and acetylacetonato ligands, [Pt(C11H7BrN)(C5H7O2)], consists of two crystallographically non-equivalent dimers, each stacked by π-π interactions with distances of ≃ 3.4Å. In both dimers, the platinum(II) complexes are arranged antiparallel to each other. Each complex exhibits a slightly distorted square-planar coordination environment around the central Pt(II) atom. The dihedral angles between two chelate rings including the PtII atom in these complexes are 0.08(12) and 1.54(9)°.
KW - acetylacetonato ligand
KW - crystal structure
KW - cyclometalated complex
KW - platinum(II)
KW - π-π interactions
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U2 - 10.1107/S2056989015017478
DO - 10.1107/S2056989015017478
M3 - Article
AN - SCOPUS:84948667780
SN - 2056-9890
VL - 71
SP - 1259
EP - 1261
JO - Acta Crystallographica Section E: Crystallographic Communications
JF - Acta Crystallographica Section E: Crystallographic Communications
ER -