Crystal structures of dimeric manganese(III) complexes of tetradentate Schiff-base ligands with ancillary axial donors

Kenichi Oyaizu; Takeshi Nakagawa; Eishun Tsuchida

doi:10.1016/S0020-1693(00)00135-3

Crystal structures of dimeric manganese(III) complexes of tetradentate Schiff-base ligands with ancillary axial donors

Kenichi Oyaizu, Takeshi Nakagawa, Eishun Tsuchida^*

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

16 被引用数 (Scopus)

抄録

[N,N'-Ethylenebis(salicylideneaminato)]manganese(III) benzoate ([Mn(salen)(O₂CC₆H₅)] crystallized to form a solid-state dimer in which the Mn(salen) moiety is linked to its neighbor by two shared phenolate oxygen atoms, in striking contrast to the linear polymeric structure formed with bridging acetate ligands. A substantial cavity between the two manganese atoms was then produced by the weak coordination of the phenolate oxygen to the neighboring manganese bearing benzoate in a monodentate mode. (C) 2000 Elsevier Science S.A.

本文言語	English
ページ（範囲）	184-188
ページ数	5
ジャーナル	Inorganica Chimica Acta
巻	305
号	2
DOI	https://doi.org/10.1016/S0020-1693(00)00135-3
出版ステータス	Published - 2000 7月 28

ASJC Scopus subject areas

物理化学および理論化学
無機化学
材料化学

文献へのアクセス

10.1016/S0020-1693(00)00135-3

他のファイルとリンク

引用スタイル

@article{aa71373b982242c7a22b5d18464594a0,

title = "Crystal structures of dimeric manganese(III) complexes of tetradentate Schiff-base ligands with ancillary axial donors",

abstract = "[N,N'-Ethylenebis(salicylideneaminato)]manganese(III) benzoate ([Mn(salen)(O2CC6H5)] crystallized to form a solid-state dimer in which the Mn(salen) moiety is linked to its neighbor by two shared phenolate oxygen atoms, in striking contrast to the linear polymeric structure formed with bridging acetate ligands. A substantial cavity between the two manganese atoms was then produced by the weak coordination of the phenolate oxygen to the neighboring manganese bearing benzoate in a monodentate mode. (C) 2000 Elsevier Science S.A.",

keywords = "Crystal structures, Dinuclear complexes, Manganese complexes, Schiff base complexes",

author = "Kenichi Oyaizu and Takeshi Nakagawa and Eishun Tsuchida",

note = "Funding Information: This work was partially supported by a Grant-in-Aid for Scientific Research Program (No. 11650878) from the Ministry of Education, Science, Sports and Culture, Japan.",

year = "2000",

month = jul,

day = "28",

doi = "10.1016/S0020-1693(00)00135-3",

language = "English",

volume = "305",

pages = "184--188",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier BV",

number = "2",

}

TY - JOUR

T1 - Crystal structures of dimeric manganese(III) complexes of tetradentate Schiff-base ligands with ancillary axial donors

AU - Oyaizu, Kenichi

AU - Nakagawa, Takeshi

AU - Tsuchida, Eishun

N1 - Funding Information: This work was partially supported by a Grant-in-Aid for Scientific Research Program (No. 11650878) from the Ministry of Education, Science, Sports and Culture, Japan.

PY - 2000/7/28

Y1 - 2000/7/28

N2 - [N,N'-Ethylenebis(salicylideneaminato)]manganese(III) benzoate ([Mn(salen)(O2CC6H5)] crystallized to form a solid-state dimer in which the Mn(salen) moiety is linked to its neighbor by two shared phenolate oxygen atoms, in striking contrast to the linear polymeric structure formed with bridging acetate ligands. A substantial cavity between the two manganese atoms was then produced by the weak coordination of the phenolate oxygen to the neighboring manganese bearing benzoate in a monodentate mode. (C) 2000 Elsevier Science S.A.

AB - [N,N'-Ethylenebis(salicylideneaminato)]manganese(III) benzoate ([Mn(salen)(O2CC6H5)] crystallized to form a solid-state dimer in which the Mn(salen) moiety is linked to its neighbor by two shared phenolate oxygen atoms, in striking contrast to the linear polymeric structure formed with bridging acetate ligands. A substantial cavity between the two manganese atoms was then produced by the weak coordination of the phenolate oxygen to the neighboring manganese bearing benzoate in a monodentate mode. (C) 2000 Elsevier Science S.A.

KW - Crystal structures

KW - Dinuclear complexes

KW - Manganese complexes

KW - Schiff base complexes

UR - http://www.scopus.com/inward/record.url?scp=0034725545&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0034725545&partnerID=8YFLogxK

U2 - 10.1016/S0020-1693(00)00135-3

DO - 10.1016/S0020-1693(00)00135-3

M3 - Article

AN - SCOPUS:0034725545

SN - 0020-1693

VL - 305

SP - 184

EP - 188

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 2

ER -

Crystal structures of dimeric manganese(III) complexes of tetradentate Schiff-base ligands with ancillary axial donors

抄録

ASJC Scopus subject areas

文献へのアクセス

他のファイルとリンク

フィンガープリント

引用スタイル