抄録
This paper describes the selective formation of a cyclic tetramer from a readily synthesized metalloporphyrin with two self-complementary quadruple hydrogen-bonding units. The extremely strong quadruple hydrogen-bonding unit, 2-ureido-4[1H]-pyrimidinone, enabled the formation of a stable cyclic tetramer based on a tetraphenylporphyrin derivative over a wide concentration range. This hydrogen-bonded tetramer is a new functional unit for use in a higher-ordered architecture of a supramolecular porphyrin assembly.
本文言語 | English |
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ページ(範囲) | 2225-2228 |
ページ数 | 4 |
ジャーナル | Organic Letters |
巻 | 8 |
号 | 11 |
DOI | |
出版ステータス | Published - 2006 5月 25 |
ASJC Scopus subject areas
- 分子医療