Development of pressure sensitive molecular film composed of platinum porphyrin complex

Yu Matsuda*, Hideo Mori, Hiroki Yamaguchi, Yoshiki Sakazaki, Toru Uchida, Tomohide Niimi


研究成果: Article査読


The pressure-sensitive paint (PSP) has potential as a diagnostic tool for pressure measurement in the high Knudsen number regime because it works as a so-called "molecular sensor". However, there are few reports concerning application of the PSP to micro devices, because the conventional PSP is too thick owing to the use of polymer binder. In our previous work, we have adopted Langmuir-Blodgett (LB) technique to fabricate pressure sensitive molecular films (PSMFs) using Pd (II) Mesoporphyrin IX (PdMP). The PSMF based on PdMP has pressure sensitivity at low pressure range (below 130 Pa) only. In this study, we have constructed PSMF composed of Pt (II) Mesoporphyrin IX (PtMP) to apply pressure measurement near atmospheric pressure condition. The pressure sensitivity and temperature dependency of PSMF based on PtMP has tested, and it is clarified that the PSMF of PtMP has equivalent pressure sensitivity of polymer PSP and the temperature dependency of PSMF is dominated by non-radiative deactivation process of excited luminophore molecule. The pressure distribution on the solid surface interacting with supersonic free-jet can be measured with PSMF composed of PtMP.

ジャーナルNihon Kikai Gakkai Ronbunshu, B Hen/Transactions of the Japan Society of Mechanical Engineers, Part B
出版ステータスPublished - 2008 2月

ASJC Scopus subject areas

  • 凝縮系物理学
  • 機械工学


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