DIFFERENTIAL THERMOGRAVIMETRY ANALYSIS AND MASS SPECTROMETRY STUDIES OF TRANSITION METAL MACROCYCLES DISPERSED ON HIGH AREA CARBON.

Daniel Alberto Scherson; A. A. Tanaka; R. Lattimer; E. B. Yeager

DIFFERENTIAL THERMOGRAVIMETRY ANALYSIS AND MASS SPECTROMETRY STUDIES OF TRANSITION METAL MACROCYCLES DISPERSED ON HIGH AREA CARBON.

Daniel Alberto Scherson^*, A. A. Tanaka, R. Lattimer, E. B. Yeager

^*この研究の対応する著者

研究成果: Conference article › 査読

抄録

A temperature of 400C is sufficient to induce a partial (or total) degradation of metal free, cobalt and a mu -oxo form of iron tetramethoxyphenyl porphyrins dispersed on high area carbons. This conclusion was drawn on the basis of slow pyrolysis - mass spectrometry (SP-MS) experiments performed under conditions very similar to those employed in the preparation of highly catalytic materials used in gas-fed O//2 cathodes of the fuel cell type. This work will present SP-MS and differential gravimetry results for these ultra purified materials both in bulk form and supported on high area Vulcan XC-72 carbon.

本文言語	English
ページ（範囲）	915-916
ページ数	2
ジャーナル	Electrochemical Society Extended Abstracts
巻	85-1
出版ステータス	Published - 1985 1月 1
外部発表	はい

ASJC Scopus subject areas

工学（全般）

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「DIFFERENTIAL THERMOGRAVIMETRY ANALYSIS AND MASS SPECTROMETRY STUDIES OF TRANSITION METAL MACROCYCLES DISPERSED ON HIGH AREA CARBON.」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

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abstract = "A temperature of 400C is sufficient to induce a partial (or total) degradation of metal free, cobalt and a mu -oxo form of iron tetramethoxyphenyl porphyrins dispersed on high area carbons. This conclusion was drawn on the basis of slow pyrolysis - mass spectrometry (SP-MS) experiments performed under conditions very similar to those employed in the preparation of highly catalytic materials used in gas-fed O//2 cathodes of the fuel cell type. This work will present SP-MS and differential gravimetry results for these ultra purified materials both in bulk form and supported on high area Vulcan XC-72 carbon.",

author = "Scherson, {Daniel Alberto} and Tanaka, {A. A.} and R. Lattimer and Yeager, {E. B.}",

year = "1985",

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T1 - DIFFERENTIAL THERMOGRAVIMETRY ANALYSIS AND MASS SPECTROMETRY STUDIES OF TRANSITION METAL MACROCYCLES DISPERSED ON HIGH AREA CARBON.

AU - Scherson, Daniel Alberto

AU - Tanaka, A. A.

AU - Lattimer, R.

AU - Yeager, E. B.

PY - 1985/1/1

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N2 - A temperature of 400C is sufficient to induce a partial (or total) degradation of metal free, cobalt and a mu -oxo form of iron tetramethoxyphenyl porphyrins dispersed on high area carbons. This conclusion was drawn on the basis of slow pyrolysis - mass spectrometry (SP-MS) experiments performed under conditions very similar to those employed in the preparation of highly catalytic materials used in gas-fed O//2 cathodes of the fuel cell type. This work will present SP-MS and differential gravimetry results for these ultra purified materials both in bulk form and supported on high area Vulcan XC-72 carbon.

AB - A temperature of 400C is sufficient to induce a partial (or total) degradation of metal free, cobalt and a mu -oxo form of iron tetramethoxyphenyl porphyrins dispersed on high area carbons. This conclusion was drawn on the basis of slow pyrolysis - mass spectrometry (SP-MS) experiments performed under conditions very similar to those employed in the preparation of highly catalytic materials used in gas-fed O//2 cathodes of the fuel cell type. This work will present SP-MS and differential gravimetry results for these ultra purified materials both in bulk form and supported on high area Vulcan XC-72 carbon.

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JF - Electrochemical Society Extended Abstracts

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