Effect of electrodeposited Ca film on hydrogen entry behavior into API-X65

Hirotaka Kato, Kazuki Isshiki, Jun'ichi Sakai

    研究成果: Article査読

    抄録

    The objective in this study was to clarify the effect of electrodeposited Ca film on hydrogen entry behavior into API-X65 by measurements of hydrogen content and an electrochemical hydrogen permeation technique in Ca(OH)2 and NaOH solutions under constant current cathodic hydrogen charging. As a result, hydrogen content in the steel cathodically charged in Ca(OH)2 solution was larger than that in NaOH solution, which was attributed to the formation of Ca film. And hydrogen permeation efficiency on the area where electrodeposited Ca film didn't exist (reaction part) was measured by the electrochemical hydrogen permeation technique. From 0 to 40% of electrodeposited Ca film coverage, it was clarified that hydrogen permeation efficiency increased and hydrogen entry was enhanced at the reaction part. It was clarified that hydrogen permeation efficiency decreased and hydrogen entry was inhibited at the reaction part when the electrodeposited Ca film coverage was more than 40%.

    本文言語English
    ページ(範囲)311-314
    ページ数4
    ジャーナルZairyo to Kankyo/ Corrosion Engineering
    64
    7
    出版ステータスPublished - 2015

    ASJC Scopus subject areas

    • 電気化学
    • 材料化学
    • 金属および合金
    • 表面、皮膜および薄膜

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