EFFECT OF UNDERPOTENTIAL DEPOSITION ON THE KINETICS OF THE CHROMOUS-CHROMIC COUPLE.

C. D. Wu; E. J. Calvo; Daniel Alberto Scherson; M. Reid; E. Yeager

EFFECT OF UNDERPOTENTIAL DEPOSITION ON THE KINETICS OF THE CHROMOUS-CHROMIC COUPLE.

C. D. Wu^*, E. J. Calvo, Daniel Alberto Scherson, M. Reid, E. Yeager

^*この研究の対応する著者

研究成果: Paper › 査読

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The aim of this work has been to investigate the effect of the modification of Ag surface by simultaneous underpotential deposition (upd) of Pb and Tl on the electroreduction of Cr(OH//2)Cl**2** plus . The upd layers of Pb and Tl inhibit the electroreduction of Cr(OH//2)//5Cl**2** plus and the effect is a linear function of the upd metal coverage. The most likely explanation is that the interaction of the halide as a bridging species with the upd covered surface is less favorable than that with the substrate alone.

本文言語	English
ページ	412-414
ページ数	3
出版ステータス	Published - 1984 12月 1
外部発表	はい

ASJC Scopus subject areas

工学（全般）

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abstract = "The aim of this work has been to investigate the effect of the modification of Ag surface by simultaneous underpotential deposition (upd) of Pb and Tl on the electroreduction of Cr(OH//2)Cl**2** plus . The upd layers of Pb and Tl inhibit the electroreduction of Cr(OH//2)//5Cl**2** plus and the effect is a linear function of the upd metal coverage. The most likely explanation is that the interaction of the halide as a bridging species with the upd covered surface is less favorable than that with the substrate alone.",

author = "Wu, {C. D.} and Calvo, {E. J.} and Scherson, {Daniel Alberto} and M. Reid and E. Yeager",

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AU - Wu, C. D.

AU - Calvo, E. J.

AU - Scherson, Daniel Alberto

AU - Reid, M.

AU - Yeager, E.

PY - 1984/12/1

Y1 - 1984/12/1

N2 - The aim of this work has been to investigate the effect of the modification of Ag surface by simultaneous underpotential deposition (upd) of Pb and Tl on the electroreduction of Cr(OH//2)Cl**2** plus . The upd layers of Pb and Tl inhibit the electroreduction of Cr(OH//2)//5Cl**2** plus and the effect is a linear function of the upd metal coverage. The most likely explanation is that the interaction of the halide as a bridging species with the upd covered surface is less favorable than that with the substrate alone.

AB - The aim of this work has been to investigate the effect of the modification of Ag surface by simultaneous underpotential deposition (upd) of Pb and Tl on the electroreduction of Cr(OH//2)Cl**2** plus . The upd layers of Pb and Tl inhibit the electroreduction of Cr(OH//2)//5Cl**2** plus and the effect is a linear function of the upd metal coverage. The most likely explanation is that the interaction of the halide as a bridging species with the upd covered surface is less favorable than that with the substrate alone.

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EFFECT OF UNDERPOTENTIAL DEPOSITION ON THE KINETICS OF THE CHROMOUS-CHROMIC COUPLE.

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