TY - JOUR
T1 - Electric field-assisted NSR process for lean NOx reduction at low temperatures
AU - Shigemoto, Ayaka
AU - Inoda, Yuki
AU - Ukai, Chihiro
AU - Higo, Takuma
AU - Oka, Kohei
AU - Sekine, Yasushi
N1 - Publisher Copyright:
© 2024 The Royal Society of Chemistry.
PY - 2024/1/4
Y1 - 2024/1/4
N2 - Lean-burn engines are gaining attention for their lower CO2 emissions, higher thermal efficiency, and improved fuel economy compared to traditional combustion engines. However, they present some difficulty for reducing nitrogen oxides (NOx) because of residual oxygen. To address this difficulty, NOx storage reduction (NSR) system, which combines noble metals and NOx adsorbents, is developed as a viable approach. But it requires cyclic operation, which adversely affects fuel efficiency. A novel approach proposed in this work is electric field-assisted lean NOx reduction, which applies an electric field to the NSR catalyst during lean conditions. This innovation uses surplus vehicle electricity for exhaust purification, enhances hydrogen transfer, and improves NOx reduction, even at low temperatures. Tests with a 3 wt% Pt-16 wt% BaO/CeO2 catalyst demonstrate markedly higher NOx conversion to N2 (13.1% vs. 2.9% without an electric field). This process is effective with extended electric field exposure, doubling the conversion rate. Electric field-assisted lean NOx reduction, by improving NSR technology, can enhance NOx conversion efficiency, reduce emissions, and optimize fuel efficiency in lean-burn engines.
AB - Lean-burn engines are gaining attention for their lower CO2 emissions, higher thermal efficiency, and improved fuel economy compared to traditional combustion engines. However, they present some difficulty for reducing nitrogen oxides (NOx) because of residual oxygen. To address this difficulty, NOx storage reduction (NSR) system, which combines noble metals and NOx adsorbents, is developed as a viable approach. But it requires cyclic operation, which adversely affects fuel efficiency. A novel approach proposed in this work is electric field-assisted lean NOx reduction, which applies an electric field to the NSR catalyst during lean conditions. This innovation uses surplus vehicle electricity for exhaust purification, enhances hydrogen transfer, and improves NOx reduction, even at low temperatures. Tests with a 3 wt% Pt-16 wt% BaO/CeO2 catalyst demonstrate markedly higher NOx conversion to N2 (13.1% vs. 2.9% without an electric field). This process is effective with extended electric field exposure, doubling the conversion rate. Electric field-assisted lean NOx reduction, by improving NSR technology, can enhance NOx conversion efficiency, reduce emissions, and optimize fuel efficiency in lean-burn engines.
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U2 - 10.1039/d3cc05189g
DO - 10.1039/d3cc05189g
M3 - Article
C2 - 38204414
AN - SCOPUS:85182376833
SN - 1359-7345
VL - 60
SP - 1563
EP - 1566
JO - Chemical Communications
JF - Chemical Communications
IS - 12
ER -