@article{1f79bc75cf50487fad19fe964a9c7d89,
title = "Elucidation of the reaction mechanism on dry reforming of methane in an electric field by in situ DRIFTs",
abstract = "With increasing expectations for carbon neutrality, dry reforming is anticipated for direct conversion of methane and carbon dioxide: the main components of biogas. We have found that dry reforming of methane in an electric field using a Pt/CeO2 catalyst proceeds with sufficient rapidity even at a low temperature of about 473 K. The effect of the electric field (EF) on dry reforming was investigated using kinetic analysis, in situ DRIFTs, XPS, and DFT calculation. In situ DRIFTs and XPS measurements indicated that the amount of carbonate, which is an adsorbed species of CO2, increased with the application of EF. XPS measurements also confirmed the reduction of CeO2 by the reaction of surface oxygen and CH4.",
author = "Naoya Nakano and Maki Torimoto and Hiroshi Sampei and Reiji Yamashita and Ryota Yamano and Koki Saegusa and Ayaka Motomura and Kaho Nagakawa and Hideaki Tsuneki and Shuhei Ogo and Yasushi Sekine",
note = "Funding Information: This work was partly achieved through the use of the supercomputer system at the information initiative center, Hokkaido University, Sapporo, Japan. This work was the result of using characterization equipments (JEM-2100F and Versa Probe II: Material Characterization Central Laboratory in Waseda University) shared in MEXT Project for promoting public utilization of advanced research infrastructure (Program for supporting construction of core facilities) Grant Number JPMXS0440500021 and JPMXS0440500022. Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry",
year = "2022",
month = mar,
day = "23",
doi = "10.1039/d2ra00402j",
language = "English",
volume = "12",
pages = "9036--9043",
journal = "RSC Advances",
issn = "2046-2069",
publisher = "Royal Society of Chemistry",
number = "15",
}