Enantioselective incorporation of dicarboxylate guests by octacalcium phosphate

Taishi Yokoi; Shingo Machida; Yoshiyuki Sugahara; Masami Hashimoto; Satoshi Kitaoka

doi:10.1039/c7cc01169e

Enantioselective incorporation of dicarboxylate guests by octacalcium phosphate

Taishi Yokoi^*, Shingo Machida, Yoshiyuki Sugahara, Masami Hashimoto, Satoshi Kitaoka

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

14 被引用数 (Scopus)

抄録

Enantioselectivity by octacalcium phosphate (OCP) is revealed through the incorporation of (S)-(-)-methylsuccinic acid (MeSuc) into its crystal lattice, with hardly any (R)-(+)-MeSuc incorporated. This phenomenon clearly indicates that OCP recognizes the steric structures of guest molecules, extending chiral recognition in inorganic materials to three-dimensional crystal growth.

本文言語	English
ページ（範囲）	6524-6527
ページ数	4
ジャーナル	Chemical Communications
巻	53
号	48
DOI	https://doi.org/10.1039/c7cc01169e
出版ステータス	Published - 2017 1月 1

ASJC Scopus subject areas

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学 (全般)
表面、皮膜および薄膜
金属および合金
材料化学

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AU - Kitaoka, Satoshi

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AB - Enantioselectivity by octacalcium phosphate (OCP) is revealed through the incorporation of (S)-(-)-methylsuccinic acid (MeSuc) into its crystal lattice, with hardly any (R)-(+)-MeSuc incorporated. This phenomenon clearly indicates that OCP recognizes the steric structures of guest molecules, extending chiral recognition in inorganic materials to three-dimensional crystal growth.

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Enantioselective incorporation of dicarboxylate guests by octacalcium phosphate

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