TY - JOUR
T1 - Enantioselective nucleophilic substitution of a 6,6-bicyclic dienyl acetate by palladium-chiral phosphine catalyst
AU - Shimizu, Isao
AU - Matsumoto, Yoshiyuki
AU - Nishikawa, Masahiro
AU - Kawahara, Tamotsu
AU - Satake, Akiharu
AU - Yamamoto, Akio
PY - 1998
Y1 - 1998
N2 - The enantioselective nucleophilic substitution of (±)-2β-acetoxy-4aβ-methyl-2,3,4,4a,5,6-hexahydronaphthalene with dimethyl malonate anion was performed in the presence of palladium-chiral ligand catalysts to give optically active 2-di(methoxycarbonyl)methyl-4a-methyl-2,3,4,4a,5,6-hexahydronaphthalenes.
AB - The enantioselective nucleophilic substitution of (±)-2β-acetoxy-4aβ-methyl-2,3,4,4a,5,6-hexahydronaphthalene with dimethyl malonate anion was performed in the presence of palladium-chiral ligand catalysts to give optically active 2-di(methoxycarbonyl)methyl-4a-methyl-2,3,4,4a,5,6-hexahydronaphthalenes.
UR - http://www.scopus.com/inward/record.url?scp=0032274823&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0032274823&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0032274823
SN - 0366-7022
SP - 983
EP - 984
JO - Chemistry Letters
JF - Chemistry Letters
IS - 10
ER -