Enantioselective total synthesis of (-)-erinacine B

Hideaki Watanabe; Masashi Takano; Akinori Umino; Toshiya Ito; Hiroyuki Ishikawa; Masahisa Nakada

doi:10.1021/ol0628816

Enantioselective total synthesis of (-)-erinacine B

Hideaki Watanabe, Masashi Takano, Akinori Umino, Toshiya Ito, Hiroyuki Ishikawa, Masahisa Nakada^*

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

47 被引用数 (Scopus)

抄録

(Chemical Equation Presented) The first enantioselective total synthesis of (-)-erinacine B has been achieved. Our approach features convergent construction of the 5-6-7 tricyclic cyathane core system via chiral building blocks prepared using asymmetric catalysis developed by us and highly stereoselective construction of all stereogenic centers in the aglycon.

本文言語	English
ページ（範囲）	359-362
ページ数	4
ジャーナル	Organic Letters
巻	9
号	2
DOI	https://doi.org/10.1021/ol0628816
出版ステータス	Published - 2007 1月 18

ASJC Scopus subject areas

生化学
物理化学および理論化学
有機化学

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10.1021/ol0628816

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abstract = "(Chemical Equation Presented) The first enantioselective total synthesis of (-)-erinacine B has been achieved. Our approach features convergent construction of the 5-6-7 tricyclic cyathane core system via chiral building blocks prepared using asymmetric catalysis developed by us and highly stereoselective construction of all stereogenic centers in the aglycon.",

author = "Hideaki Watanabe and Masashi Takano and Akinori Umino and Toshiya Ito and Hiroyuki Ishikawa and Masahisa Nakada",

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AU - Watanabe, Hideaki

AU - Takano, Masashi

AU - Umino, Akinori

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AU - Ishikawa, Hiroyuki

AU - Nakada, Masahisa

PY - 2007/1/18

Y1 - 2007/1/18

N2 - (Chemical Equation Presented) The first enantioselective total synthesis of (-)-erinacine B has been achieved. Our approach features convergent construction of the 5-6-7 tricyclic cyathane core system via chiral building blocks prepared using asymmetric catalysis developed by us and highly stereoselective construction of all stereogenic centers in the aglycon.

AB - (Chemical Equation Presented) The first enantioselective total synthesis of (-)-erinacine B has been achieved. Our approach features convergent construction of the 5-6-7 tricyclic cyathane core system via chiral building blocks prepared using asymmetric catalysis developed by us and highly stereoselective construction of all stereogenic centers in the aglycon.

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Enantioselective total synthesis of (-)-erinacine B

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