@article{7ada8a67c5e646db9a2abdb8e151945b,
title = "Gold(I)-catalyzed 10-endo-dig-selective cycloisomerization of N-(2-anilinobenzyl)propargylamines",
abstract = "– The cationic gold(I)-catalyzed 10-endo-dig-selective cycloisomerization of N-(2-anilinobenzyl)propargylamine derivatives was developed. The reaction proceeded smoothly under mild conditions to give dibenzodiazecines. The catalytic construction of an entropically and enthalpically disfavored ten-membered ring was achieved by using a highly nucleophilic 3,5-dimethoxyanilino group as a reaction site.",
author = "Mamoru Ito and Daisuke Inoue and Asahi Takaki and Kanyiva, {Kyalo Stephen} and Takanori Shibata",
note = "Funding Information: This work was supported by Mitsubishi Materials Corporation and Waseda University Joint Cooperation Publisher Copyright: {\textcopyright} 2020 The Japan Institute of Heterocyclic Chemistry",
year = "2020",
doi = "10.3987/COM-19-S(F)13",
language = "English",
volume = "101",
pages = "195--208",
journal = "Heterocycles",
issn = "0385-5414",
publisher = "Japan Institute of Heterocyclic Chemistry",
number = "1",
}