抄録
Ionic transport behavior across an electropolymerized polypyrrole/polyazulene composite film was investigated by using ac impedance analysis, and its charge-discharge characteristics were also studied. Co-electropolymerization of pyrrole and azulene was well defined and fairly stoichiometric in propylene carbonate solution. The charge capacity for the composite films showed a remarkable increase for films with about 50 to 75% of azulene monomer content, and the behavior was correlated with morphological and diffusivity changes. The charge-discharge characteristics were examined for cells with a lithium anode and various polypyrrole/polyazulene composite cathodes. Pure polypyrrole cathodes behaved exactly like a capacitor at low frequency, while pure polyazulene cathodes showed excellent rechargeable behavior with very flat discharge curves. Composite cathodes showed intermediate behavior.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 494-499 |
| ページ数 | 6 |
| ジャーナル | Journal of the Electrochemical Society |
| 巻 | 137 |
| 号 | 2 |
| DOI | |
| 出版ステータス | Published - 1990 2月 |
ASJC Scopus subject areas
- 電子材料、光学材料、および磁性材料
- 再生可能エネルギー、持続可能性、環境
- 表面、皮膜および薄膜
- 電気化学
- 材料化学
UN SDG
この成果は、次の持続可能な開発目標に貢献しています
