In Situ Atomic Force Microscopy Imaging of Electroprecipitated Nickel Hydrous Oxide Films in Alkaline Electrolytes

Rong rong Chen, Yibo Mo, Daniel Alberto Scherson*

*この研究の対応する著者

研究成果: Article査読

22 被引用数 (Scopus)

抄録

In situ atomic force microscopy images of nickel hydrous oxide films electrodeposited on the basal plane of highly oriented pyrolytic graphite in alkaline electrolytes have shown that a stepwise oxidation leads to irreversible formation of wide crevices throughout the material. Upon subsequent stepwise reduction, the gaps close leaving a hairline type crack which follows the profile of the crevice. These potential induced structural rearrangements have been attributed to stresses induced by differences in the densities of the nickel hydrous oxide in the two oxidation states.

本文言語English
ページ(範囲)3933-3936
ページ数4
ジャーナルLangmuir
10
11
DOI
出版ステータスPublished - 1994 11月 1
外部発表はい

ASJC Scopus subject areas

  • 材料科学(全般)
  • 凝縮系物理学
  • 表面および界面
  • 分光学
  • 電気化学

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