Intramolecular Consecutive Dehydro-Diels–Alder Reaction for the Catalytic and Enantioselective Construction of Axial Chirality

Takanori Shibata*, Ayato Sekine, Akihito Mitake, Kyalo Stephen Kanyiva

*この研究の対応する著者

研究成果: Article査読

33 被引用数 (Scopus)

抄録

Consecutive thermal and metal-catalyzed dehydro-Diels–Alder (DDA) reactions of sulfur-tethered tetraynes, possessing a 1,3-diyne moiety, proceeded efficiently, and axial chirality was achieved for the resulting dibenzothiophenyl moieties. Chiral-rhodium catalysis realized a highly enantioselective synthesis, and transformations into bis(benzocarbazole) derivatives were also achieved.

本文言語English
ページ(範囲)15862-15865
ページ数4
ジャーナルAngewandte Chemie - International Edition
57
48
DOI
出版ステータスPublished - 2018 11月 26

ASJC Scopus subject areas

  • 触媒
  • 化学一般

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