Ion-induced transformation of magnetism in a bimetallic CuFe Prussian blue analogue

Masashi Okubo; Daisuke Asakura; Yoshifumi Mizuno; Tetsuichi Kudo; Haoshen Zhou; Atsushi Okazawa; Norimichi Kojima; Kazumichi Ikedo; Takashi Mizokawa; Itaru Honma

doi:10.1002/anie.201102048

Ion-induced transformation of magnetism in a bimetallic CuFe Prussian blue analogue

Masashi Okubo^*, Daisuke Asakura, Yoshifumi Mizuno, Tetsuichi Kudo, Haoshen Zhou, Atsushi Okazawa, Norimichi Kojima, Kazumichi Ikedo, Takashi Mizokawa, Itaru Honma

^*この研究の対応する著者

研究成果: Article › 査読

83 被引用数 (Scopus)

抄録

Li ions for degaussing: A Prussian blue analogue with Fe^III and Cu^II ions bridged by CN ligands underwent a ferromagnetic transition induced by ferromagnetic interactions between the Fe and Cu ions (see picture). Li ions penetrating into this ferromagnetic framework eliminated the ferromagnetic interaction and effected the formation of a paramagnetic framework. The ferromagnetism was recovered by extracting the Li ions.

本文言語	English
ページ（範囲）	6269-6273
ページ数	5
ジャーナル	Angewandte Chemie - International Edition
巻	50
号	28
DOI	https://doi.org/10.1002/anie.201102048
出版ステータス	Published - 2011 7月 4
外部発表	はい

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化学 (全般)

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title = "Ion-induced transformation of magnetism in a bimetallic CuFe Prussian blue analogue",

abstract = "Li ions for degaussing: A Prussian blue analogue with FeIII and CuII ions bridged by CN ligands underwent a ferromagnetic transition induced by ferromagnetic interactions between the Fe and Cu ions (see picture). Li ions penetrating into this ferromagnetic framework eliminated the ferromagnetic interaction and effected the formation of a paramagnetic framework. The ferromagnetism was recovered by extracting the Li ions.",

keywords = "M{\"o}ssbauer spectroscopy, coordination chemistry, electrochemistry, electronic structure, magnetic materials",

author = "Masashi Okubo and Daisuke Asakura and Yoshifumi Mizuno and Tetsuichi Kudo and Haoshen Zhou and Atsushi Okazawa and Norimichi Kojima and Kazumichi Ikedo and Takashi Mizokawa and Itaru Honma",

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doi = "10.1002/anie.201102048",

language = "English",

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T1 - Ion-induced transformation of magnetism in a bimetallic CuFe Prussian blue analogue

AU - Okubo, Masashi

AU - Asakura, Daisuke

AU - Mizuno, Yoshifumi

AU - Kudo, Tetsuichi

AU - Zhou, Haoshen

AU - Okazawa, Atsushi

AU - Kojima, Norimichi

AU - Ikedo, Kazumichi

AU - Mizokawa, Takashi

AU - Honma, Itaru

PY - 2011/7/4

Y1 - 2011/7/4

N2 - Li ions for degaussing: A Prussian blue analogue with FeIII and CuII ions bridged by CN ligands underwent a ferromagnetic transition induced by ferromagnetic interactions between the Fe and Cu ions (see picture). Li ions penetrating into this ferromagnetic framework eliminated the ferromagnetic interaction and effected the formation of a paramagnetic framework. The ferromagnetism was recovered by extracting the Li ions.

AB - Li ions for degaussing: A Prussian blue analogue with FeIII and CuII ions bridged by CN ligands underwent a ferromagnetic transition induced by ferromagnetic interactions between the Fe and Cu ions (see picture). Li ions penetrating into this ferromagnetic framework eliminated the ferromagnetic interaction and effected the formation of a paramagnetic framework. The ferromagnetism was recovered by extracting the Li ions.

KW - Mössbauer spectroscopy

KW - coordination chemistry

KW - electrochemistry

KW - electronic structure

KW - magnetic materials

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U2 - 10.1002/anie.201102048

DO - 10.1002/anie.201102048

M3 - Article

C2 - 21618377

AN - SCOPUS:79959889128

SN - 1433-7851

VL - 50

SP - 6269

EP - 6273

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 28

ER -

Ion-induced transformation of magnetism in a bimetallic CuFe Prussian blue analogue

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