@article{544828df9d0c42508494329c6a9b193f,
title = "Layer-by-Layer Motif Heteroarchitecturing of N,S-Codoped Reduced Graphene Oxide-Wrapped Ni/NiS Nanoparticles for the Electrochemical Oxidation of Water",
abstract = "A new heterostructured material is synthesized with lamellar arrangements in nanoscale precision through an innovative synthetic approach. The self-assembled Ni-based cyano-bridged coordination polymer flakes (Ni-CP) and graphene oxide (GO) nanosheets with a layered morphology (Ni-CP/GO) are used as precursors for the synthesis of multicomponent hybrid materials. Annealing of Ni-CP/GO in nitrogen at 450 °C allows the formation of Ni3C/rGO nanocomposites. Grinding Ni-CP/GO and thiourea and annealing under the same conditions produces N,S-codoped reduced GO-wrapped NiS2 flakes (NiS2/NS-rGO). Interestingly, further heating up to 550 °C allows the phase transformation of NiS2 into NiS accompanied by the formation of a face-centered cubic (FCC-Ni) metal phase between NS-rGO layers (FCC-Ni-NiS/NS-rGO). Among all the materials, the resulting FCC-Ni-NiS/NS-rGO exhibits good electrocatalytic activity and stability toward the oxygen evolution reaction (OER) owing to the synergistic effect of multiphases, the well-designed alternating layered structures on the nanoscale with abundant active sites.",
keywords = "electrocatalysis, heterostructures, metal carbides, metal sulfides, nanohybrids",
author = "Zakaria, {Mohamed Barakat} and Yanna Guo and Jongbeom Na and Rafat Tahawy and Toyohiro Chikyow and El-Said, {Waleed A.} and El-Hady, {Deia A.} and Wael Alshitari and Yusuke Yamauchi and Jianjian Lin",
note = "Funding Information: This work was supported by the China Postdoctoral Science Foundation (2019M652339) and the National Natural Science Foundation of China (NSFC; 61604070). This work was performed in part at the Queensland node of the Australian National Fabrication Facility, a company established under the National Collaborative Research Infrastructure Strategy to provide nano and microfabrication facilities for Australia's researchers. This work was funded by the University of Jeddah, Saudi Arabia, under grant No. UJ‐02‐010‐ICGR. The authors, therefore, acknowledge with thanks the university's technical and financial support. J.L. is supported by the Taishan Scholarship Project of Shandong Province (tsqn201909115). Funding Information: This work was supported by the China Postdoctoral Science Foundation (2019M652339) and the National Natural Science Foundation of China (NSFC; 61604070). This work was performed in part at the Queensland node of the Australian National Fabrication Facility, a company established under the National Collaborative Research Infrastructure Strategy to provide nano and microfabrication facilities for Australia's researchers. This work was funded by the University of Jeddah, Saudi Arabia, under grant No. UJ-02-010-ICGR. The authors, therefore, acknowledge with thanks the university's technical and financial support. J.L. is supported by the Taishan Scholarship Project of Shandong Province (tsqn201909115). Publisher Copyright: {\textcopyright} 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
year = "2020",
month = jun,
day = "19",
doi = "10.1002/cssc.202000159",
language = "English",
volume = "13",
pages = "3269--3276",
journal = "ChemSusChem",
issn = "1864-5631",
publisher = "Wiley-VCH Verlag",
number = "12",
}