Low-temperature laser photolysis of benzophenone in neat diethylaniline: Optical detection of an excited triplet state with a strong charge-transfer structure at 77 K

Mikio Hoshino; Hiroshi Seki; Masao Kaneko; Kazuhiko Kinoshita; Haruo Shizuka

doi:10.1016/0009-2614(86)80109-9

Low-temperature laser photolysis of benzophenone in neat diethylaniline: Optical detection of an excited triplet state with a strong charge-transfer structure at 77 K

Mikio Hoshino^*, Hiroshi Seki, Masao Kaneko, Kazuhiko Kinoshita, Haruo Shizuka

^*この研究の対応する著者

研究成果: Article › 査読

1 被引用数 (Scopus)

抄録

Benzophenone forms a weak complex with diethylaniline in the ground state at 77 K. Laser photolysis studies carried out for a neat diethylaniline solution of benzophenone at 77 K reveal that the excited triplet state of the weak complex has a strong charge-transfer structure and exhibits a transient spectrum composed of the benzophenone anion radical and the cation radical of diethylaniline.

本文言語	English
ページ（範囲）	209-212
ページ数	4
ジャーナル	Chemical Physics Letters
巻	132
号	2
DOI	https://doi.org/10.1016/0009-2614(86)80109-9
出版ステータス	Published - 1986 12月 5
外部発表	はい

ASJC Scopus subject areas

物理化学および理論化学
分光学
凝縮系物理学
原子分子物理学および光学
表面および界面

文献へのアクセス

10.1016/0009-2614(86)80109-9

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引用スタイル

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AU - Kinoshita, Kazuhiko

AU - Shizuka, Haruo

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