Multinuclear Cu-catalysts based on SPINOL-PHOS in asymmetric conjugate addition of organozinc reagents

Kohei Endo; Daisuke Hamada; Sayuri Yakeishi; Mika Ogawa; Takanori Shibata

doi:10.1021/ol300748d

Multinuclear Cu-catalysts based on SPINOL-PHOS in asymmetric conjugate addition of organozinc reagents

Kohei Endo^*, Daisuke Hamada, Sayuri Yakeishi, Mika Ogawa, Takanori Shibata

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

36 被引用数 (Scopus)

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Multinuclear Cu/Zn complex-catalyzed efficient asymmetric conjugate addition of organozinc reagents to acyclic and cyclic enones has been developed in the presence of a wide variety of regioisomeric chiral diols bearing phosphorus moieties as ligands. The regioisomeric SPINOL-PHOS ligands based on a SPINOL architecture showed an unexpected inversion of stereoselectivity.

本文言語	English
ページ（範囲）	2342-2345
ページ数	4
ジャーナル	Organic Letters
巻	14
号	9
DOI	https://doi.org/10.1021/ol300748d
出版ステータス	Published - 2012 5月 4

ASJC Scopus subject areas

生化学
物理化学および理論化学
有機化学

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10.1021/ol300748d

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AU - Hamada, Daisuke

AU - Yakeishi, Sayuri

AU - Ogawa, Mika

AU - Shibata, Takanori

PY - 2012/5/4

Y1 - 2012/5/4

N2 - Multinuclear Cu/Zn complex-catalyzed efficient asymmetric conjugate addition of organozinc reagents to acyclic and cyclic enones has been developed in the presence of a wide variety of regioisomeric chiral diols bearing phosphorus moieties as ligands. The regioisomeric SPINOL-PHOS ligands based on a SPINOL architecture showed an unexpected inversion of stereoselectivity.

AB - Multinuclear Cu/Zn complex-catalyzed efficient asymmetric conjugate addition of organozinc reagents to acyclic and cyclic enones has been developed in the presence of a wide variety of regioisomeric chiral diols bearing phosphorus moieties as ligands. The regioisomeric SPINOL-PHOS ligands based on a SPINOL architecture showed an unexpected inversion of stereoselectivity.

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Multinuclear Cu-catalysts based on SPINOL-PHOS in asymmetric conjugate addition of organozinc reagents

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