Novel electroactive polyelectrolyte with alternating seleno- and selenoniophenylene units

Kenji Miyatake; Tadahiro Ishikawa; Eishun Tsuchida

doi:10.1021/ma9902596

Novel electroactive polyelectrolyte with alternating seleno- and selenoniophenylene units

Kenji Miyatake, Tadahiro Ishikawa, Eishun Tsuchida

大学院先進理工学研究科

研究成果: Article › 査読

4 被引用数 (Scopus)

抄録

Poly(phenylselenonio-1,4-phenyleneseleno-1,4-phenylene triflate) containing selenoether and phenylselenonio groups was prepared by the polycondensation of diphenyl selenide and benzeneseleninic acid in triflic acid. The polymerization was also shown to proceed for diphenyl ether and diphenyl sulfide to give the corresponding poly (aryleneselenonium triflate)s. The polymer exhibited reversible redox waves at 0.70 V (vs Ag/AgCl) and semiconductivity of 5 × 10^-6S cm^-1 when doped with FeCl₃.

本文言語	English
ページ（範囲）	4497-4499
ページ数	3
ジャーナル	Macromolecules
巻	32
号	13
DOI	https://doi.org/10.1021/ma9902596
出版ステータス	Published - 1999 6月 29

ASJC Scopus subject areas

有機化学
ポリマーおよびプラスチック
無機化学
材料化学

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title = "Novel electroactive polyelectrolyte with alternating seleno- and selenoniophenylene units",

abstract = "Poly(phenylselenonio-1,4-phenyleneseleno-1,4-phenylene triflate) containing selenoether and phenylselenonio groups was prepared by the polycondensation of diphenyl selenide and benzeneseleninic acid in triflic acid. The polymerization was also shown to proceed for diphenyl ether and diphenyl sulfide to give the corresponding poly (aryleneselenonium triflate)s. The polymer exhibited reversible redox waves at 0.70 V (vs Ag/AgCl) and semiconductivity of 5 × 10-6S cm-1 when doped with FeCl3.",

author = "Kenji Miyatake and Tadahiro Ishikawa and Eishun Tsuchida",

year = "1999",

month = jun,

day = "29",

doi = "10.1021/ma9902596",

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T1 - Novel electroactive polyelectrolyte with alternating seleno- and selenoniophenylene units

AU - Miyatake, Kenji

AU - Ishikawa, Tadahiro

AU - Tsuchida, Eishun

PY - 1999/6/29

Y1 - 1999/6/29

N2 - Poly(phenylselenonio-1,4-phenyleneseleno-1,4-phenylene triflate) containing selenoether and phenylselenonio groups was prepared by the polycondensation of diphenyl selenide and benzeneseleninic acid in triflic acid. The polymerization was also shown to proceed for diphenyl ether and diphenyl sulfide to give the corresponding poly (aryleneselenonium triflate)s. The polymer exhibited reversible redox waves at 0.70 V (vs Ag/AgCl) and semiconductivity of 5 × 10-6S cm-1 when doped with FeCl3.

AB - Poly(phenylselenonio-1,4-phenyleneseleno-1,4-phenylene triflate) containing selenoether and phenylselenonio groups was prepared by the polycondensation of diphenyl selenide and benzeneseleninic acid in triflic acid. The polymerization was also shown to proceed for diphenyl ether and diphenyl sulfide to give the corresponding poly (aryleneselenonium triflate)s. The polymer exhibited reversible redox waves at 0.70 V (vs Ag/AgCl) and semiconductivity of 5 × 10-6S cm-1 when doped with FeCl3.

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JO - Macromolecules

JF - Macromolecules

IS - 13

ER -

Novel electroactive polyelectrolyte with alternating seleno- and selenoniophenylene units

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