On the correlations between Sr:Ca substitution and structural modulation in the Bi-2212 phase

Y. Oikawa; P. P. Saligan; K. Koizumi; H. Enomoto; Y. Takano; K. Sekizawa; E. Uchida; H. Ozaki

doi:10.1007/BF02562826

On the correlations between Sr:Ca substitution and structural modulation in the Bi-2212 phase

Y. Oikawa^*, P. P. Saligan, K. Koizumi, H. Enomoto, Y. Takano, K. Sekizawa, E. Uchida, H. Ozaki

^*この研究の対応する著者

創造理工学部

研究成果: Article › 査読

抄録

XPS and chemical titration both were carried out on Bi_2+xSr_l.8CaCu₂O_z and Bi₂Sr_l.8-yCa_l+yCu₂0_zprepared by solid state reaction in order to investigate the correlation between the structural modulation and the mutual substitution of atoms. There was no clear evidence about the correlation between the modulation period by XRD and the site occupancies of Sr and Ca by XPS. However, there was a tendency that Bi mean valence by titration inereased with increasing excess oxygen content and modulation period. The former one indicates the charge compensation and the latter one suggests the possibility of the origin of the structural modulation except for the excess oxygen.

本文言語	English
ページ（範囲）	1423-1424
ページ数	2
ジャーナル	Czechoslovak Journal of Physics
巻	46
号	SUPPL. 3
DOI	https://doi.org/10.1007/BF02562826
出版ステータス	Published - 1996 12月 1

ASJC Scopus subject areas

物理学および天文学（全般）

文献へのアクセス

10.1007/BF02562826

他のファイルとリンク

引用スタイル

@article{fd7c45cc599b421593a955e5ad1e7d60,

title = "On the correlations between Sr:Ca substitution and structural modulation in the Bi-2212 phase",

abstract = "XPS and chemical titration both were carried out on Bi2+xSrl.8CaCu2Oz and Bi2Srl.8-yCal+yCu20zprepared by solid state reaction in order to investigate the correlation between the structural modulation and the mutual substitution of atoms. There was no clear evidence about the correlation between the modulation period by XRD and the site occupancies of Sr and Ca by XPS. However, there was a tendency that Bi mean valence by titration inereased with increasing excess oxygen content and modulation period. The former one indicates the charge compensation and the latter one suggests the possibility of the origin of the structural modulation except for the excess oxygen.",

author = "Y. Oikawa and Saligan, {P. P.} and K. Koizumi and H. Enomoto and Y. Takano and K. Sekizawa and E. Uchida and H. Ozaki",

year = "1996",

month = dec,

day = "1",

doi = "10.1007/BF02562826",

language = "English",

volume = "46",

pages = "1423--1424",

journal = "Czechoslovak Journal of Physics",

issn = "0011-4626",

publisher = "Springer Netherlands",

number = "SUPPL. 3",

}

TY - JOUR

T1 - On the correlations between Sr:Ca substitution and structural modulation in the Bi-2212 phase

AU - Oikawa, Y.

AU - Saligan, P. P.

AU - Koizumi, K.

AU - Enomoto, H.

AU - Takano, Y.

AU - Sekizawa, K.

AU - Uchida, E.

AU - Ozaki, H.

PY - 1996/12/1

Y1 - 1996/12/1

N2 - XPS and chemical titration both were carried out on Bi2+xSrl.8CaCu2Oz and Bi2Srl.8-yCal+yCu20zprepared by solid state reaction in order to investigate the correlation between the structural modulation and the mutual substitution of atoms. There was no clear evidence about the correlation between the modulation period by XRD and the site occupancies of Sr and Ca by XPS. However, there was a tendency that Bi mean valence by titration inereased with increasing excess oxygen content and modulation period. The former one indicates the charge compensation and the latter one suggests the possibility of the origin of the structural modulation except for the excess oxygen.

AB - XPS and chemical titration both were carried out on Bi2+xSrl.8CaCu2Oz and Bi2Srl.8-yCal+yCu20zprepared by solid state reaction in order to investigate the correlation between the structural modulation and the mutual substitution of atoms. There was no clear evidence about the correlation between the modulation period by XRD and the site occupancies of Sr and Ca by XPS. However, there was a tendency that Bi mean valence by titration inereased with increasing excess oxygen content and modulation period. The former one indicates the charge compensation and the latter one suggests the possibility of the origin of the structural modulation except for the excess oxygen.

UR - http://www.scopus.com/inward/record.url?scp=77958090138&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=77958090138&partnerID=8YFLogxK

U2 - 10.1007/BF02562826

DO - 10.1007/BF02562826

M3 - Article

AN - SCOPUS:77958090138

SN - 0011-4626

VL - 46

SP - 1423

EP - 1424

JO - Czechoslovak Journal of Physics

JF - Czechoslovak Journal of Physics

IS - SUPPL. 3

ER -

On the correlations between Sr:Ca substitution and structural modulation in the Bi-2212 phase

抄録

ASJC Scopus subject areas

文献へのアクセス

他のファイルとリンク

フィンガープリント

引用スタイル