Organic radical battery: Nitroxide polymers as a cathode-active material

Hiroyuki Nishide; Shigeyuki Iwasa; Yong Jin Pu; Takeo Suga; Kentaro Nakahara; Masaharu Satoh

doi:10.1016/j.electacta.2004.02.052

Organic radical battery: Nitroxide polymers as a cathode-active material

Hiroyuki Nishide^*, Shigeyuki Iwasa, Yong Jin Pu, Takeo Suga, Kentaro Nakahara, Masaharu Satoh

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

413 被引用数 (Scopus)

抄録

Purely organic-derived nitroxide radicals, including their polymer derivative, poly(2,2,6,6-tetramethylpiperidinyloxy methacrylate) (PTMA), were characterized as a new class of cathode-active materials for lithium batteries. PTMA was stable at ambient conditions, had a tunable solubility and processability, and could undergo thermal runaway without any odor and ash. The nitroxide radicals displayed a reversible and very rapid redox to form their oxoammonium salts, which enabled a high power-rate performance during the charge and discharge process of the battery.

本文言語	English
ページ（範囲）	827-831
ページ数	5
ジャーナル	Electrochimica Acta
巻	50
号	2-3 SPEC. ISS.
DOI	https://doi.org/10.1016/j.electacta.2004.02.052
出版ステータス	Published - 2004 11月 30

ASJC Scopus subject areas

化学工学（全般）
電気化学

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10.1016/j.electacta.2004.02.052

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title = "Organic radical battery: Nitroxide polymers as a cathode-active material",

abstract = "Purely organic-derived nitroxide radicals, including their polymer derivative, poly(2,2,6,6-tetramethylpiperidinyloxy methacrylate) (PTMA), were characterized as a new class of cathode-active materials for lithium batteries. PTMA was stable at ambient conditions, had a tunable solubility and processability, and could undergo thermal runaway without any odor and ash. The nitroxide radicals displayed a reversible and very rapid redox to form their oxoammonium salts, which enabled a high power-rate performance during the charge and discharge process of the battery.",

keywords = "Cathode materials, Lithium secondary batteries, Polymer batteries, Radical molecules",

author = "Hiroyuki Nishide and Shigeyuki Iwasa and Pu, {Yong Jin} and Takeo Suga and Kentaro Nakahara and Masaharu Satoh",

note = "Funding Information: This work was partially supported by the NEDO Project on “High Power Density Radical Battery for Data-Backup”, and 21COE “Practical Nano-Chemistry” from MEXT, Japan. ",

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doi = "10.1016/j.electacta.2004.02.052",

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T2 - Nitroxide polymers as a cathode-active material

AU - Nishide, Hiroyuki

AU - Iwasa, Shigeyuki

AU - Pu, Yong Jin

AU - Suga, Takeo

AU - Nakahara, Kentaro

AU - Satoh, Masaharu

N1 - Funding Information: This work was partially supported by the NEDO Project on “High Power Density Radical Battery for Data-Backup”, and 21COE “Practical Nano-Chemistry” from MEXT, Japan.

PY - 2004/11/30

Y1 - 2004/11/30

N2 - Purely organic-derived nitroxide radicals, including their polymer derivative, poly(2,2,6,6-tetramethylpiperidinyloxy methacrylate) (PTMA), were characterized as a new class of cathode-active materials for lithium batteries. PTMA was stable at ambient conditions, had a tunable solubility and processability, and could undergo thermal runaway without any odor and ash. The nitroxide radicals displayed a reversible and very rapid redox to form their oxoammonium salts, which enabled a high power-rate performance during the charge and discharge process of the battery.

AB - Purely organic-derived nitroxide radicals, including their polymer derivative, poly(2,2,6,6-tetramethylpiperidinyloxy methacrylate) (PTMA), were characterized as a new class of cathode-active materials for lithium batteries. PTMA was stable at ambient conditions, had a tunable solubility and processability, and could undergo thermal runaway without any odor and ash. The nitroxide radicals displayed a reversible and very rapid redox to form their oxoammonium salts, which enabled a high power-rate performance during the charge and discharge process of the battery.

KW - Cathode materials

KW - Lithium secondary batteries

KW - Polymer batteries

KW - Radical molecules

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Organic radical battery: Nitroxide polymers as a cathode-active material

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